膜厚对热处理聚二甲基硅氧烷薄膜表面润湿性的影响

doi:10.3901/JME.2022.03.186

机械工程学报 ›› 2022, Vol. 58 ›› Issue (3): 186-193.doi: 10.3901/JME.2022.03.186

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膜厚对热处理聚二甲基硅氧烷薄膜表面润湿性的影响

陈荣昕¹, 张炜², 孙魏¹, 叶家鑫¹, 刘小君¹, 刘焜¹

1. 合肥工业大学摩擦学研究所合肥 230009;
2. 福建工程学院机械与汽车工程学院福州 350118

收稿日期:2021-04-19 修回日期:2021-08-29 出版日期:2022-02-05 发布日期:2022-03-19
通讯作者: 刘焜(通信作者),男,1963年出生,博士,教授,博士研究生导师。主要研究方向为表面摩擦学。E-mail:liukun@hfut.edu.cn
作者简介:陈荣昕,女,1994年出生,博士研究生。主要研究方向为界面润湿。E-mail:chenrongxin@mail.hfut.edu.cn
基金资助:
国家自然科学基金（51875152，51875153，51975174）和福建省自然科学基金（2020J01869）资助项目。

Influence of Film Thickness on Surface Wettability of Heat Treated Polydimethylsiloxane Films

CHEN Rongxin¹, ZHANG Wei², SUN Wei¹, YE Jiaxin¹, LIU Xiaojun¹, LIU Kun¹

1. Institute of Tribology, Hefei University of Technology, Hefei 230009;
2. School of Mechanical & Automotive Engineering, Fujian University of Technology, Fuzhou 350118

Received:2021-04-19 Revised:2021-08-29 Online:2022-02-05 Published:2022-03-19

摘要/Abstract

摘要： 针对聚二甲基硅氧烷（PDMS）薄膜润湿性这一重要表面特性，通过旋涂法制备不同厚度PDMS薄膜，通过接触角测量、表面形貌观测、薄膜厚度分析、红外化学光谱分析等方式对热处理前、后PDMS薄膜表面润湿性及其物理、化学状态进行表征分析，探究膜厚因素对最终热处理后PDMS薄膜润湿特性的影响机理。研究表明，不同厚度状态下热处理后H-PDMS薄膜表面具有亲水-疏水-超疏水-超亲水的润湿状态差异；同时，从表面形貌变化、截面厚度变化及化学键等物理、化学层面分析表明SiO₂颗粒的生成及SiO₂颗粒粒径大小和颗粒之间的堆叠状态变化可对膜厚差异导致热处理后H-PDMS薄膜润湿性不同做出良好解释。本研究为进一步剖析PDMS薄膜润湿特性提供理论基础，并为通过控制PDMS薄膜厚度从而实现其热处理后润湿状态调控提供方法指引。

关键词: 聚二甲基硅氧烷(PDMS), 润湿, 膜厚, 表面形貌, 光谱分析

Abstract: Aimed at the surface wettability of polydimethylsiloxane (PDMS) film, which is the important surface characteristic, PDMS films with different thickness are prepared by spin coating method. The surface wettability, physical characteristics and chemical characteristics of PDMS films before and after heat treatment are analyzed by contact angle measurement, surface morphology observation, film thickness analysis and infrared chemical spectrum analysis. The influence of film thickness on the wettability of heat treatment PDMS film is explored. The results show that the surface of H-PDMS films has different wettability states, including hydrophilic, hydrophobic, superhydrophobic, and superhydrophilic. Moreover, the physical and chemical analysis of surface morphology, cross-section thickness and chemical bonds show that the formation of SiO₂ particles, the change of SiO₂ particle size, and the change of stacking state of SiO₂particles can cause the difference of wettability of H-PDMS films. This study would provide a theoretical basis for further investigation on the wettability characteristics of PDMS films, and can provide a method guide for changing the wettability of heat treated PDMS films by controlling the thickness of PDMS films.

Key words: polydimethylsiloxane(PDMS), wettability, film thickness, surface topography, FTIR

中图分类号:

TH117
TB34

陈荣昕, 张炜, 孙魏, 叶家鑫, 刘小君, 刘焜. 膜厚对热处理聚二甲基硅氧烷薄膜表面润湿性的影响[J]. 机械工程学报, 2022, 58(3): 186-193.

CHEN Rongxin, ZHANG Wei, SUN Wei, YE Jiaxin, LIU Xiaojun, LIU Kun. Influence of Film Thickness on Surface Wettability of Heat Treated Polydimethylsiloxane Films[J]. Journal of Mechanical Engineering, 2022, 58(3): 186-193.

参考文献

[1] WU Y,SHEN Y,TAO J,et al. Facile spraying fabrication of highly flexible and mechanically robust superhydrophobic F-SiO₂@PDMS coatings for self-cleaning and drag-reduction applications[J]. New Journal of Chemistry,2018,42:18208-18216.
[2] 林金堂,王嘉鑫,丘志榕,等. 多孔聚二甲基硅氧烷薄膜的制备及摩擦发电性能研究[J]. 电子元件与材料,2020,39(7):90-94,101. LIN Jintang,WANG Jiaxin,QIU Zhirong,et al. Preparation and triboelectric properties of porous polydimethylsiloxane film[J]. Electronic Components and Materials,2020,39(7):90-94,101.
[3] 徐书洁,段玉岗,丁玉成,等. PDMS微流控芯片复型模具的新型快速制作方法[J]. 机械工程学报,2007,43(6):105-109. XU Shujie,DUAN Yugang,DING Yucheng,et al. New method for rapid fabricating masters of PDMS-based microfluidic devices[J]. Journal of Mechanical Engineering,2007,43(6):105-109.
[4] SEGHIR R,ARSCOTT S. Extended PDMS stiffness range for flexible systems[J]. Sensors and Actuators A:Physical,2015,230:33-39.
[5] 吴珍,田继兰,黄鲸慧,等. PDMS动力黏度对PDMS/PVDF复合渗透汽化膜形貌及优先透醇性能影响[J]. 石油学报(石油加工),2021,37(2):345-351. WU Zhen,TIAN Jilan,HUANG Jinghui,et al. Effect of PDMS dynamic viscosity on morphology and ethanol separation of PDMS/PVDF composite membrane[J]. Acta Petrolei Sinica(Petroleum Processing Section),2021,37(2):345-351.
[6] KHORASANI M,MIRZADEH H,KERMANI Z. Wettability of porous polydimethylsiloxane surface:Morphology study[J]. Applied Surface Science,2005,242(3-4):339-345.
[7] KUJAWSKA A,KNOZOWSKA K,KUJAWA J,et al. Fabrication of PDMS based membranes with improved separation efficiency in hydrophobic pervaporation[J]. Separation and Purification Technology,2020,234:116092.
[8] KAMEYA Y. Wettability modification of polydime-thylsiloxane surface by fabricating micropillar and microhole arrays[J]. Materials Letters,2017,196:320-323.
[9] 焦云龙,叶家鑫,刘小君,等.表面润湿性对橡胶滑动接触界面摩擦特性的影响[J]. 机械工程学报,2019,55(1):106-111. JIAO Yunlong,YE Jiaxin,LIU Xiaojun,et al. Influence of surface wettability on the sliding frictional property of NBR rubber[J]. Journal of Mechanical Engineering,2019,55(1):106-111.
[10] GAO J,ZHAO J,LIU L,et al. Dimensional effects of polymer pillar arrays on hydrophobicity[J]. Surface Engineering,2016,32(2):125-131.
[11] PAN S,KOTA A K,MABRY J M,et al. Superomniphobic surfaces for effective chemical shielding[J]. Journal of the American Chemical Society,2013,135(2):578-581.
[12] SU X,LI H,LAI X,et al. Polydimethylsiloxane-based superhydrophobic surfaces on steel substrate:fabrication,reversibly extreme wettability and oil-water separation[J]. ACS Applied Materials & Interfaces,2017,9(3):3131-3141.
[13] PAN S,WANG N,XIONG D,et al. Fabrication of superhydrophobic coating via spraying method and its applications in anti-icing and anti-corrosion[J]. Applied Surface Science,2016,389:547-553.
[14] ATTHI N,SRIPUMKHAI W,PATTAMANG P,et al. Superhydrophobic property enhancement on guard ring micro-patterned PDMS with simple flame treatment[J]. Japanese Journal of Applied Physics,2020,59(SI):SIIJ05.
[15] HU H,LI S,YING C,et al. Hydrophilic PDMS with a sandwich-like structure and no loss of mechanical properties and optical transparency[J]. Applied Surface Science,2020,503:144126.
[16] MAJI D,LAHIRI S K,DAS S. Study of hydrophilicity and stability of chemically modified PDMS surface using piranha and KOH solution[J]. Surface and Interface Analysis,2012,44(1):62-69.
[17] LIU X,XU Y,BEN K,et al. Transparent,durable and thermally stable PDMS-derived superhydrophobic surfaces[J]. Applied Surface Science,2015,339:94-101.
[18] SEO J,LEE L P. Effects on wettability by surfactant accumulation/depletion in bulk polydimethylsiloxane (PDMS)[J]. Sensors and Actuators B:Chemical,2006,119(1):192-198.
[19] PENG C,WU J,TSAI C. Wettability distribution on the surface treated by plasma jet at different flow rates for microfluidic applications[J]. IEEE Transactions on Plasma Science,2021,49(1):168-176.
[20] KARAPANAGIOTIS I,MANOUDIS P N,ZURBA A,et al. From hydrophobic to superhydrophobic and superhydrophilic siloxanes by thermal treatment[J]. Langmuir,2014,30(44):13235-13243.
[21] ALAM E,YADAV S,SCHNEIDER J J,et al. Imbibition of water into substrates prepared by thermal treatment of polydimethylsiloxane layers[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,521:69-77.
[22] FENG J,ZHAO Y. Influence of different amount of Au on the wetting behavior of PDMS membrane[J]. Biomed Microdevices,2008,10:65-72.
[23] CAMINO G,LOMAKIN S M,LAGEARD M. Thermal polydimethylsiloxane degradation. Part 2. The degradation mechanisms[J]. Polymer,2002,43:2011-2015.

膜厚对热处理聚二甲基硅氧烷薄膜表面润湿性的影响

Influence of Film Thickness on Surface Wettability of Heat Treated Polydimethylsiloxane Films

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