金刚石粒度及添加量对大气环境感应钎涂层耐磨性的影响

doi:10.3901/JME.2023.12.225

机械工程学报 ›› 2023, Vol. 59 ›› Issue (12): 225-235.doi: 10.3901/JME.2023.12.225

扫码分享

金刚石粒度及添加量对大气环境感应钎涂层耐磨性的影响

龙伟民^1,2,3, 刘大双⁴, 吴爱萍¹, 钟素娟², 王德成⁵

1. 清华大学机械工程学院北京 100084;
2. 郑州机械研究所有限公司郑州 450001;
3. 中机智能装备创新研究院(宁波)有限公司宁波 315700;
4. 合肥工业大学材料科学与工程学院合肥 230009;
5. 机械科学研究总院集团有限公司北京 100044

收稿日期:2021-09-14 修回日期:2023-04-01 出版日期:2023-06-20 发布日期:2023-08-15
通讯作者: 龙伟民(通信作者),男,1966年出生,研究员,博士研究生导师。主要研究方向为钎焊材料、钎焊工艺与设备、钎涂熔敷技术、焊接结构失效分析。E-mail:longweimin@camsouth.com.cn
基金资助:
国家自然科学基金(U2004186)和河南省重大科技专项(191110111000)资助项目。

Influence of Size and Content on the Wear Resistance of Induction Brazing Diamond Coating in Air

LONG Weimin^1,2,3, LIU Dashuang⁴, WU Aiping¹, ZHONG Sujuan², WANG Decheng⁵

1. Department of Mechanical Engineering, Tsinghua University, Beijing 100084;
2. Zhengzhou Research Institute of Mechanical Engineering Co., Ltd., Zhengzhou 450001;
3. China Innovation Academy of Intelligent Equipment (Ningbo) Co., Ltd., Ningbo 315700;
4. School of Material Science and Engineering, Hefei University of Technology, Hefei 230009;
5. China Academy of Machinery Science and Technology Group Co., Ltd., Beijing 100044

Received:2021-09-14 Revised:2023-04-01 Online:2023-06-20 Published:2023-08-15

摘要/Abstract

摘要： 金刚石是自然界中最坚硬的物质，因其具有良好的耐磨性能，广泛应用于切削、磨削等行业。利用钎涂技术制备金刚石工具，具有独特优势。钎涂层中的金刚石粒度及添加量是影响涂层耐磨性的关键因素，为此，试验研究金刚石添加量及粒度对大气环境感应钎涂层界面组织及耐磨性的影响规律，探讨金刚石钎涂层的耐磨机制。结果表明，Cr元素在金刚石微粒/Ni基钎料合金界面处形成了宽度约2 μm的富集带。当金刚石添加量达到15%时，可原位生成一定比例的碳化物，且碳化物类型为Cr₇C₃。同质量分数添加金刚石微粒(210～280 μm)的钎涂层耐磨性要优于添加颗粒(700～840 μm)的钎涂层。对于添加不同含量金刚石微粒的钎涂层而言，金刚石添加量为20%时涂层耐磨性最优，当金刚石添加量超过20%，耐磨性不增反降。钎涂层中金刚石在磨损过程中，呈现完整、钝化、裂纹、破碎、脱落等形式。

关键词: 金刚石, 钎涂, 感应加热, 耐磨性

Abstract: Diamond is the hardest material in nature. Because of its good wear resistance, it is widely used in cutting, grinding and other industries. Using brazing technology to prepare diamond tools has unique advantages. The diamond content and particle size in the brazing coating are the key factors affecting the wear resistance of brazing diamond. Therefore, the effects of diamond size and content on the interface structure and wear resistance of induction brazing coating in air were studied, and their wear resistance mechanism was discussed. The results show that Cr element forms a width of 2 μm enrichment zone at the interface between diamond particles and Ni based solder alloy. When the addition of diamond reaches 15%, the proportion of Cr₇C₃ carbide in nickel base brazing coating reaches the maximum. Under the test conditions, the wear resistance of brazing coating with the fraction of diamond particles (210-280 μm) is better than that with particles (841/707 μm). With the increase of diamond content, the wear resistance of diamond brazing coating becomes better. When the diamond content is 20%, the wear resistance of coating is the best. When the diamond content exceeds 20%, the wear resistance decreases. During the wear process, diamonds are forms of integrity, passivation, cracking, breaking and falling off.

Key words: diamond, brazing coating, induction heating, wear resistance

中图分类号:

TH425

龙伟民, 刘大双, 吴爱萍, 钟素娟, 王德成. 金刚石粒度及添加量对大气环境感应钎涂层耐磨性的影响[J]. 机械工程学报, 2023, 59(12): 225-235.

LONG Weimin, LIU Dashuang, WU Aiping, ZHONG Sujuan, WANG Decheng. Influence of Size and Content on the Wear Resistance of Induction Brazing Diamond Coating in Air[J]. Journal of Mechanical Engineering, 2023, 59(12): 225-235.

参考文献

[1] 张康,黄亦翔,赵帅,等. 基于t-SNE数据驱动模型的盾构装备刀盘健康评估[J]. 机械工程学报,2019,55(7):35-42. ZHANG Kang,HUANG Yixiang,ZHAO Shuai,et al. Health assessment of shield equipment cutterhead based on t-SNE data-driven model[J]. Journal of Mechanical Engineering,2019,55(7):35-42.
[2] 曹忠溪,周玉梅,张凤林,等. 钎焊金刚石耐磨涂层制备及其磨损性能[J]. 金刚石与磨料磨具工程,2019,39(3):93-101. CAO Zhongxi,ZHOU Yumei,ZHANG Fenglin,et al. Preparation and wear properties of brazed diamond wear-resistant coatings[J]. Diamond & Abrasives Engineering,2019,39(3):93-101.
[3] 张启运,庄鸿寿. 钎焊手册[M]. 3版. 北京:机械工业出版社,2018. ZHANG Qiyun,ZHUANG Hongshou. Brazing handbook[M]. 3rd ed. Beijing:China Machine Press,2018.
[4] 陆善平,郭义. 钎焊工艺对WC-Co/NiCrBSi复合涂层性能的影响[J]. 材料研究学报,1999,13(2):188-193. LU Shanping,GUO Yi. The effect of brazing parameters on the properties of WC-Co/NiCrBSi composite coating[J]. Chinese Journal of Materials Research,1999,13(2):188-193.
[5] 侯立宁,石荟琦,时海芳. Ni基复合WC粉末钎涂层组织及性能研究[J]. 热加工工艺,2012,41(24):173-175. HOU Lining,SHI Huiqi,SHI Haifang. Study on microstructure and mechanical properties of WC/nickel-based powder composite coating[J]. Hot Working Technology,2012,41(24):173-175.
[6] MA B J,YANG G L,BU F N. Study of brazed diamond micro-powder burs fabricated using induction brazing with either an amorphous or a crystalline Ni-based filler alloy[J]. International Journal of Refractory Metals & Hard Materials,2016,62:58-63.
[7] 张小红,申景园,孙宇,等. 挤压致密超细WC/纳米Al₂O₃弥散强化铜基复合材料的组织性能研究[J]. 粉末冶金技术,2019,37(6):422-427. ZHANG Xiaohong,SHEN Jingyuan,SUN Yu,et al. Study on the microstructure and properties of dispersion-reinforced Cu-based composites by ultrafine WC and nano-sized Al₂O₃ particles via extrusion densification[J]. Powder Metallurgy Technology,2019,37(6):422-427.
[8] 龙伟民,郝庆乐,傅玉灿,等. 金刚石工具钎焊用连接材料研究进展[J]. 材料导报,2020,34(23):142-148. LONG Weimin,HAO Qingle,FU Yucan,et al. Research progress of filler metals for brazing diamond tools[J]. Materials Reports,2020,34(23):142-148.
[9] 李明,贾成厂,郭宏,等. Ag-Cu-Ti活性钎料真空钎焊金刚石/Cu复合材料和金刚石膜[J]. 粉末冶金技术,2013,31(6):444-450. LI Ming,JIA Chengchang,GUO Hong,et al. Study on the vacuum brazing of diamond/Cu composite material and diamond film with Ag-Cu-Ti active filler metal[J]. Powder Metallurgy Technology,2013,31(6):444-450.
[10] 陈世隐,郭佳杰,黄国钦. 基于径向基神经网络对磨削功率预测的研究[J]. 超硬材料工程,2016,28(4):33-37. CHEN Shiyin,GUO Jiajie,HUANG Guoqin. Research on prediction of grinding power based on RBF neural network[J]. Superhard Material Engineering,2016,28(4):33-37.
[11] 卢金斌,汤峰,孟普,等. Ni-Cr合金真空钎焊金刚石的热损伤分析[J]. 焊接学报,2010,31(8):25-28. LU Jinbin,TANG Feng,MENG Pu,et al. Analysis of thermal damage of Ni-Cr alloy vacuum brazing diamond[J]. Transactions of the China Welding Institution,2010,31(8):25-28.
[12] 卢金斌,徐九华. Ag-Cu-Ti钎焊金刚石的界面结构及热应力分析[J]. 稀有金属材料与工程,2009,38(4):642-646. LU Jinbin,XU Jiuhua. Analysis of the interface structure and thermal stress of Ag-Cu-Ti brazed diamond[J]. Rare Metal Materials and Engineering,2009,38(4):642-646.
[13] SUN B J,XIAO B. Comparative study on interfacial microstructure and cutting performance of tunnel furnace and vacuum furnace brazed diamond core-drill[J]. Diamond and Related Materials,2018,89:132-139.
[14] 钟素娟,张雷,宋晓国,等. 一种在旋耕刀表面制备金刚石耐磨涂层的感应钎涂装置,CN211989525U[P]. 2020-11-24. ZHONG Sujuan,ZHANG Lei,SONG Xiaoguo,et al. Induction brazing device for preparing diamond wear-resistant coating on the surface of rotary tiller,CN211989525U[P]. 2020-11-24.
[15] 詹友基,黄辉,徐西鹏. 钎焊金刚石砂轮磨削石材中金刚石粒度对磨削力的影响研究[J]. 金刚石与磨料磨具工程,2006,153(3):17-19. ZHAN Youji,HUANG Hui,XU Xipeng. Influence of diamond grit size on grinding forces when grinding stone with brazed diamond wheel[J]. Diamond & Abrasives Engineering,2006,153(3):17-19.
[16] 张国青,黄辉,徐西鹏. 钎焊单层金刚石薄壁钻头钻削工程陶瓷的研究[J]. 矿冶工程,2008(3):110-113. ZHANG Guoqing,HUANG Hui,XU Xipeng. Research on drilling engineering ceramics with brazed single layer diamond thin-walled drill[J]. Mining and Metallurgical Engineering,2008(3):110-113.
[17] 龙伟民,乔培新,王海滨,等. 粉末合成钎料的探讨[J]. 机械工程学报,2001,37(10):107-108. LONG Weimin,QIAO Peixin,WANG Haibin,et al. Discussion of powder synthetic filler materials[J]. Journal of Mechanical Engineering,2001,37(10):107-108.
[18] LONG W M,LIU D S,DONG X,et al. Laser power effects on properties of laser brazing diamond coating[J]. Surface Engineering,2020,36:1-12.
[19] LONG W M,LIU D S,WU A P,et al. Influence of laser scanning speed on the formation property of laser brazing diamond[J]. Diamond and Related Materials,2020,110:108085.
[20] 龙伟民,刘大双,张冠星,等. 感应钎涂粉末熔融及传热机制[J]. 焊接学报,2021,42(11):29-34. LONG Weimin,LIU Dashuang,ZHANG Guanxing,et al. Melting and heat transfer mechanism of powder by induction brazing coating[J]. Transactions of the China Welding Institution,2021,42(11):29-34.
[21] 龙伟民,刘大双,王博,等. 铝微粉对大气环境感应钎涂金刚石涂层性能影响[J]. 焊接学报,2021,42(12):67-71. LONG Weimin,LIU Dashuang,WANG Bo,et al. Effect of aluminum powder on properties of induction braze coated diamond layers in atmospheric environment[J]. Transactions of the China Welding Institution,2021,42(12):67-71.
[22] 徐琦. Ni基钎料钎焊金刚石工具界面结合行为及其强化机制研究[D]. 长沙:长沙理工大学,2020. XU Qi. Study on Interfacial bonding behaviors and enhancement mechanism of brazed diamond tools with Ni-based filler alloy[D]. Changsha:Changsha University of Science and Technology,2020.
[23] JACOB K T. Determination of the Gibbs energy of diamond using a solid state cell[J]. Solid State Commun.,1995,94:763-765.
[24] 曹庆忠. 涂覆金刚石的钎焊工艺研究[J]. 超硬材料工程,2019,31(1):34-39. CAO Qingzhong. Research on brazing process of coated diamond[J]. Superhard Material Engineering,2019,31(1):34-39.
[25] 刘瑶瑶. 热损伤聚晶金刚石真空摩擦学性能及其机理研究[D]. 北京:中国地质大学(北京),2018. LIU Yaoyao. Tribological properties and mechanism of thermal damaged polycrystalline diamond under vacuum conditions[D]. Beijing:China University of Geosciences,2018.
[26] 布克哈德G,齐格利希B,波勒提乌斯M,等. 用有序排列的金刚石或立方氮化硼磨料作切削加工[J]. 超硬材料工程,2006(3):50-55. BURKHARD G,ZIEGLICH B,POLETTIUS M,et al. Use ordered diamond or cubic boron nitride abrasives for cutting[J]. Superhard Material Engineering,2006(3):50-55.
[27] 李灿,刘小萍,郑强,等. 等离子喷涂含金刚石微粒的Cr₂O₃涂层干摩擦磨损性能研究[J]. 真空科学与技术学报,2016,36(8):873-879. LI Can,LIU Xiaoping,ZHENG Qiang,et al. Improvement of tribological properties of plasma sprayed Cr₂O₃ coatings by adding diamond powder[J]. Chinese Journal of Vacuum Science and Technology,2016,36(8):873-879.
[28] 沈彬. 超光滑金刚石复合薄膜的制备、摩擦学性能及应用研究[D]. 上海:上海交通大学,2009. SHEN Bin. Study on the deposition,tribological properties and applications of ultra-smooth composite diamond films[D]. Shanghai:Shanghai Jiao Tong University,2009.
[29] 黄辉,张国青,徐西鹏. 钎焊金刚石磨粒磨损性能研究[J]. 福州大学学报(自然科学版),2005(3):313-317. HUANG Hui,Zhang Guoqing,XU Xipeng. Research on the wear properties of brazed diamond abrasives[J]. Journal of Fuzhou University(Natural Science Edition),2005(3):313-317.
[30] 詹友基,黄辉,徐西鹏. 钎焊金刚石磨削石材过程中磨粒磨损状态研究[J]. 金刚石与磨料磨具工程,2007(5):10-13. ZHAN Youji,Huang Hui,XU Xipeng. Study on the abrasive wear state in the process of brazing diamond grinding stone[J]. Diamond & Abrasives Engineering,2007(5):10-13.

金刚石粒度及添加量对大气环境感应钎涂层耐磨性的影响

Influence of Size and Content on the Wear Resistance of Induction Brazing Diamond Coating in Air

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	苏志朋, 梁志强, 李娟, 王飞, 魏正义, 刘月红, 金惟薇, 马悦, 殷振, 王西彬. 钛合金微槽超声螺线辅助铣磨加工试验研究[J]. 机械工程学报, 2024, 60(9): 5-12.
[2]	王艳, 何顺, 陈奕璋, 姜晨, 钱兆峰, 陈浩毅. 超声空化辅助金刚石线锯切割单晶硅机理分析与试验验证[J]. 机械工程学报, 2024, 60(9): 114-126.
[3]	郝明武, 姚鹏, 周嘉斌, 黎月明, 梁士通, 褚东凯, 黄传真. 皮秒激光切向修整青铜结合剂金刚石砂轮的影响因素研究[J]. 机械工程学报, 2024, 60(9): 229-240.
[4]	李子清, 崔长彩, 卞素标, 李慧慧, 陆静, ORIOL Arteaga, 徐西鹏. 单晶金刚石衬底超精密加工损伤层无损测量与表征[J]. 机械工程学报, 2024, 60(4): 239-249.
[5]	袁菘, 郭晓光, 金洙吉, 康仁科, 郭东明. 金刚石高效超低损伤加工机理与工艺研究现状[J]. 机械工程学报, 2024, 60(3): 337-353.
[6]	彭文, 张丽, 李旭东, 刘军, 孙杰, 张殿华. 边部感应加热过程中的轧件热行为与温度均匀性研究[J]. 机械工程学报, 2024, 60(2): 119-131.
[7]	金强, 蒋文春, 王金光, 李刚, 张凯, 李滨, 涂善东. 承压设备厚板中频感应加热局部热处理试验研究[J]. 机械工程学报, 2023, 59(8): 83-90.
[8]	都建标, 张强, 宗文俊. 硬脆及黑色金属材料的单点金刚石车削加工技术综述[J]. 机械工程学报, 2023, 59(7): 156-175.
[9]	王慧鹏, 朱鹏华, 舒凤远, 何鹏, 刘存宇. 65Mn钢表面激光熔覆温度场模拟及性能研究[J]. 机械工程学报, 2023, 59(7): 216-224.
[10]	陈磊, 刘阳钦, 唐川, 蒋翼隆, 石鹏飞, 钱林茂. 面向超精密加工的微观材料去除机理研究进展[J]. 机械工程学报, 2023, 59(23): 229-264.
[11]	郑雷, 孙晓晗, 吕冬明, 刘子文, 朱卓志, 董香龙, 韦文东. GFRP旋转超声振动套孔加工仿真及工艺研究[J]. 机械工程学报, 2023, 59(23): 391-400.
[12]	刘汉中, 张瑞涛, 宗文俊, 孙涛. 微圆弧金刚石刀具刃磨关键技术及应用[J]. 机械工程学报, 2023, 59(21): 34-42.
[13]	潘延安, 鲍岩, 冯嘉健, 殷森, 董志刚, 康仁科. 高比重钨合金超声椭圆振动切削去除机理研究[J]. 机械工程学报, 2023, 59(21): 65-74.
[14]	张健, 肖昂, 张澳, 刘俊艺, 张明军, 彭平. Ni-Cr钎料钎焊金刚石界面强化的第一性原理计算与试验研究[J]. 机械工程学报, 2023, 59(18): 228-238.
[15]	毛雅梅, 黑鸿君, 高洁, 郑可, 于盛旺, 王垚. 钎焊金刚石研究进展及其工具的应用[J]. 机械工程学报, 2022, 58(4): 80-93.