基于3D打印技术的石墨烯基三维电极设计制造研究进展

doi:10.3901/JME.2021.23.169

机械工程学报 ›› 2021, Vol. 57 ›› Issue (23): 169-181.doi: 10.3901/JME.2021.23.169

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基于3D打印技术的石墨烯基三维电极设计制造研究进展

鲁中良¹, 李坚¹, 李赛¹, 苗恺¹, 娄晓杰², 李涤尘¹

1. 西安交通大学机械制造系统工程国家重点实验室西安 710049;
2. 西安交通大学前沿科学技术研究院西安 710054

收稿日期:2021-01-12 修回日期:2021-08-24 出版日期:2021-12-05 发布日期:2022-02-28
通讯作者: 鲁中良(通信作者),男,1977年出生,博士,教授,博士研究生导师。主要研究方向为高端/智能制造装备与系统;增材制造理论与技术;金属基/陶瓷基复合材料3D打印及其应用;航机/燃机空心涡轮叶片的增材制造技术。Email:zllu@stu.xjtu.edu.cn
作者简介:李坚,男,1994年出生,硕士研究生。主要研究方向为异形锂离子电池的增材制造(3D打印)技术。Email:2870359287@qq.com;李赛,男,1995年出生,博士研究生。主要研究方向为复合材料的增材制造(3D打印)技术。Email:lisaicd@yeah.net;苗恺,男,1990年出生,助理研究员。主要研究方向为增材制造(3D打印)技术。Email:kaimiao@xjtu.edu.cn;娄晓杰,男,1977年出生,博士,教授。主要研究方向为铁电材料的实验和理论研究。Email:xlou03@163.com;李涤尘,男,1964年出生,博士,教授,博士研究生导师。主要研究方向为增材制造(3D打印)技术与应用;生物3D打印技术与临床应用。Email:dcli@mail.xjtu.edu.cn
基金资助:
国家自然科学基金资助项目（51775418）。

Research Progress in Design and Manufacture of Graphene 3D Electrodes Based on 3D Printing Technology

LU Zhongliang¹, LI Jian¹, LI Sai¹, MIAO Kai¹, LOU Xiaojie², LI Dichen¹

1. State Key Laboratory of Mechanical Manufacturing System Engineering, Xi'an Jiaotong University, Xi'an 710049;
2. Research Institute of Frontier Science and technology, Xi'an Jiaotong University, Xi'an 710054

Received:2021-01-12 Revised:2021-08-24 Online:2021-12-05 Published:2022-02-28

摘要/Abstract

摘要： 锂离子电池因其较高的能量密度、稳定的放电平台和安全的使用环境被广泛应用于航空航天、汽车、可穿戴柔性设备等领域。目前锂离子电池的研究主要集中在薄电极（<50 μm）的设计制造，其较低的单位面积负载（<5 mg·cm^-2）严重制约了面积比容量。因此厚电极的制造（100~500 μm）将成为未来高比能量电池的研究热点。3D打印技术因其可定制化成型复杂电极结构的优势，在厚电极制造领域具有广泛的应用前景。综述了3D打印成型工艺在石墨烯基三维厚电极领域的研究进展，分析了相应3D打印工艺的成型特点（墨水性能、成型精度、适用范围）和工艺难点，展望了石墨烯基三维厚电极3D打印的发展趋势，提出了基于凝胶电解质的全电池成型工艺，为新一代高性能锂离子电池的研制提供新思路。

关键词: 3D打印, 锂离子电池, 石墨烯, 超厚电极

Abstract: Lithium ion batteries are widely used in aerospace, automotive, wearable flexible devices and other fields because of their high energy density, stable discharge platform and safe use environment. The current research of lithium-ion battery is mainly focused on the design and manufacture of thin electrode (<50 μm), whose low unit area load (<5 mg`cm^-2) severely restricts the area specific capacity. Therefore, the manufacture of thick electrode (100-500 μm) will become the research hotspot of high specific energy battery in the future. 3D printing technology has a wide application prospect in the field of thick electrode manufacturing due to its advantages of customized forming complex electrode structures. The research progress of 3D printing technology in the field of graphene based three dimensional thick electrode is reviewed. The forming characteristics of the corresponding 3D printing process (ink performance, molding accuracy, application scope) and technological difficulties are analyzed. The development trend of graphene based three-dimensional thick electrode 3D printing is prospected. The whole battery forming process based on gel electrolyte is proposed, which provides a new strategy for the development of a new generation of high performance lithium ion batteries.

Key words: 3D printing, lithium ion battery, graphene, ultra thick electrode

中图分类号:

TM911
TD404

鲁中良, 李坚, 李赛, 苗恺, 娄晓杰, 李涤尘. 基于3D打印技术的石墨烯基三维电极设计制造研究进展[J]. 机械工程学报, 2021, 57(23): 169-181.

LU Zhongliang, LI Jian, LI Sai, MIAO Kai, LOU Xiaojie, LI Dichen. Research Progress in Design and Manufacture of Graphene 3D Electrodes Based on 3D Printing Technology[J]. Journal of Mechanical Engineering, 2021, 57(23): 169-181.

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基于3D打印技术的石墨烯基三维电极设计制造研究进展

Research Progress in Design and Manufacture of Graphene 3D Electrodes Based on 3D Printing Technology

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