• CN:11-2187/TH
  • ISSN:0577-6686

›› 2009, Vol. 45 ›› Issue (1): 253-257.

• 论文 • 上一篇    下一篇

粉末球磨预处理对高硅铝合金材料组织与物理性能的影响

杨伏良;易丹青   

  1. 中南大学材料科学与工程学院;中南大学有色金属材料科学与工程教育部重点实验室
  • 发布日期:2009-01-15

Effect of Milling Pretreatment to Powders on Microstructure and Physical Properties of Al-Si Alloy Materials

YANG Fuliang; YI Danqing   

  1. School of Material Science and Engineering, Central South University Key Laboratory of Nonferrous Metal Materials Science and Engineering, Ministry of Education, Central South University
  • Published:2009-01-15

摘要: 为制备出能满足使用要求的高硅铝合金电子封装材料,采用高能球磨对Al-Si合金粉末进行氧化预处理,结合包套热挤压制备Al2O3与SiO2增强的弥散强化型铝硅复合材料,并采用透射电镜、金相显微镜及热物性测试仪,对材料显微组织、密度、气密性、热膨胀系数及热导率进行分析测试。试验结果表明:与高温空气氧化相比,粉末高能球磨后,所制备材料的晶粒更加细小,特别是硅粒子已明显细化;粉末球磨后所制备材料密度接近于理论密度,其致密度在99%左右;材料气密性很好,在1 nPa•m3•s–1以下;材料热膨胀系数随粉末球磨时间延长而下降,当球磨时间超过24 h后,材料膨胀系数小于13 K–1;随着球磨时间延长材料热导率增加,球磨32 h后,材料热导率高达145.5 W•m–1•K–1。

关键词: 电子封装, 高硅铝合金, 高能球磨, 铝硅复合材料

Abstract: In order to fabricate high silicon content aluminum alloys electronic packaging materials, Al2O3 and SiO2 dispersion strengthened metallic matrix composites (MMCs) are made by pretreatment of high-energy milling for the Al-Si alloy powder prior to hot-extrusion. The microstructure, density, air tightness, coefficient of thermal expansion and thermal conductivity (TC) are analyzed by using transmission electron microscope (TEM), metallographic microscope and thermal physical testers. Experimental results indicate the following: After Al-Si alloy powders are milled, the material grains, especially Si grains are smaller than those of the high-temperature air oxidation. The material density is close to the theoretical density, and the relative density is about 99%. The air tightness is very good and less than 1nPa•m3•s–1. The coefficient of thermal expansion decreases with prolonging milling time and less than 13K–1 after the powder is milled for 24 h. Thermal conductivity increases with prolonging milling time, after the powder is milled for 32 h, TC is up to 145.5 W•m–1•K–1.

Key words: Al-Si composite material, Electronic packaging, High-energy milling, High-silicon aluminum alloy

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