蛇纹石/纳米铜复合添加剂改善铜合金减摩抗磨性能的研究

doi:10.3901/JME.2023.18.054

机械工程学报 ›› 2023, Vol. 59 ›› Issue (18): 54-68.doi: 10.3901/JME.2023.18.054

• 特邀专栏：人工自愈与装备自主健康 • 上一篇下一篇

扫码分享

蛇纹石/纳米铜复合添加剂改善铜合金减摩抗磨性能的研究

尹艳丽¹, 于鹤龙¹, 王红美¹, 魏敏², 史佩京², 白志民³, 张伟²

1. 陆军装甲兵学院装备再制造技术国防科技重点实验室北京 100072;
2. 河北京津冀再制造产业技术研究院河间 062450;
3. 中国地质大学材料科学与工程学院北京 100083

收稿日期:2022-09-29 修回日期:2023-05-30 出版日期:2023-09-20 发布日期:2023-12-07
通讯作者: 于鹤龙(通信作者),男,1979年出生,博士,副研究员,博士研究生导师。主要研究方向为装备再制造、表面工程、摩擦学与军用新材料。E-mail:helong.yu@163.com
作者简介:尹艳丽,女,1985年出生。主要研究方向为摩擦学与再制造工程。E-mail:yinyl2009@126.com
基金资助:
国家自然科学基金面上资助项目(52075544)。

Effect of Serpentine/Nano-Cu Composites as Lubricant Additive on Tribological Properties of Tin Bronze

YIN Yanli¹, YU Helong¹, WANG Hongmei¹, WEI Min², SHI Peijing², BAI Zhimin³, ZHANG Wei²

1. National Key Laboratory for Remanufacturing, Army Academy of Armored Force, Beijing 100072;
2. Hebei Jingjinji Institute of Remanufacturing Industry & Technology, Hejian 062450;
3. School of Materials Science and Technology, China University of Geosciences, Beijing 100083

Received:2022-09-29 Revised:2023-05-30 Online:2023-09-20 Published:2023-12-07

摘要/Abstract

摘要： 采用SRV滑动磨损试验机探究表面有机改性的蛇纹石/纳米铜复合作为减摩自修复添加剂对与钢配副的锡青铜抗磨减摩性能的影响。采用扫描电子显微镜、X射线能谱仪、X射线光电子能谱仪、纳米压痕仪等分析锡青铜磨损表面和截面微观形貌、元素种类与化学状态、纳米力学性能等，并探讨蛇纹石和纳米铜复合对锡青铜的减摩抗磨机理及二者的协同作用机制。结果表明：单组分蛇纹石、纳米铜添加剂均能改善锡青铜的摩擦学性能，而复合后改善效果显著增强，与基础油润滑下相比，锡青铜的摩擦因数减小26.3%～39.2%，磨损体积降低72.6%～88.9%。摩擦过程中，蛇纹石和纳米铜发挥摩擦学正协同作用，在锡青铜表面形成了由金属氧化物、硅的氧化物、硫化物、石墨、有机物、纳米铜颗粒等构成的复合自修复膜，该自修复膜具有多层结构且较为致密光滑，厚度达到3.73 mm，其力学性能具有内部高、表面低的梯度变化，有利于提高锡青铜的摩擦学性能。

关键词: 蛇纹石, 纳米铜, 复合添加剂, 摩擦学性能, 锡青铜

Abstract: The effect of surface organic modified serpentine and nano-Cu composites as lubricant additive on tribological properties of tin bronze matching with GCr15 steel is investigated by SRV oscillating sliding wear tester. Scanning electron microscope (SEM), X-ray energy dispersive spectroscopy(EDS), X-ray photoelectron spectroscopy(XPS), and nanoindenter are used to analyze the morphology of surface and section, elemental composition, chemical state, and nano mechanical properties of worn surfaces. The friction reducing and anti-wear mechanism of serpentine and nano-Cu composites on tin bronze and their synergistic action mechanism are discussed. Results show that single component serpentine and nano-Cu additives can improve tribological properties of tin bronze, and the improvement effect is significantly enhanced after serpentine and nano-Cu compounded, and the friction coefficient and wear volume of tin bronze are reduced by 26.3%~39.2% and 72.6%~88.9% respectively, compared with base oil lubrication. Serpentine and nano-Cu play a positive role in tribology, and a composite self-repairing film composed of metal oxide, silicon oxide, sulfide, graphite, organic matter and nano-Cu particles is formed on the tin bronze surface. The self-repairing film has a multilayer and it is dense and smooth, with the thickness of 3.73 mm, and its nanohardness, elastic modulus and nanohardness/modulus have the gradient variation that low in the surface and high in the subsurface, as contributed to the improvement of the tribological behaviors of tin bronze.

Key words: serpentine, nano-Cu, composites additives, tribological behaviors, tin bronze

中图分类号:

TH117

尹艳丽, 于鹤龙, 王红美, 魏敏, 史佩京, 白志民, 张伟. 蛇纹石/纳米铜复合添加剂改善铜合金减摩抗磨性能的研究[J]. 机械工程学报, 2023, 59(18): 54-68.

YIN Yanli, YU Helong, WANG Hongmei, WEI Min, SHI Peijing, BAI Zhimin, ZHANG Wei. Effect of Serpentine/Nano-Cu Composites as Lubricant Additive on Tribological Properties of Tin Bronze[J]. Journal of Mechanical Engineering, 2023, 59(18): 54-68.

参考文献

[1] ZHANG Shizhong,GAN Xueping,CHENG Jinjuan,et al. Effect of applied load on transition behavior of wear mechanism in Cu-15Ni-8Sn alloy under oil lubrication[J]. Journal of Central South University,2017,24(8):1754-1761.
[2] YIN Bing,YIN Yansheng,LEI Yanhua,et al. Experimental and density functional studies on the corrosion behavior of the copper-nickel-tin alloy[J]. Chemical Physics Letters,2011,509(4):192-197.
[3] 付小静,李瑞川,高建国,等. 在甘油润滑下TiAlN涂层的超低摩擦和磨损特性[J].中国表面工程,2021,34(5):198-205. FU Xiaojing,LI Ruichuan,GAO Jianguo,et al. Ultralow friction and wear properties of TiAlN coatings lubricated by glycerol[J]. China Surface Engineering,2021,34(5):198-205.
[4] CHENG Jinjuan,ZHANG Shizhong,GAN Xueping,et al. Wear regime and wear mechanism map for spark-plasma-sintered Cu-15ni-8Sn-0.2Nb alloy under oil lubrication[J]. Journal of Materials Engineering and Performance,2019,28(7):4187-4196.
[5] LI Yi,ZHANG Songwei,DING Qi,et al. The corrosion and lubrication properties of 2-mercaptobenzothiazole functionalized ionic liquids for bronze[J]. Tribology International,2017,114:121-131.
[6] CAI Mingrong,LIANG Yongmin,ZHOU Feng,et al. Anticorrosion imidazolium ionic liquids as the additive in poly (ethylene glycol) for steel/Cu-Sn alloy contacts[J]. Faraday Discuss,2012,156:147-157.
[7] ESPINOSA T,SANES J,JIMENEZ A E,et al. Protic ammonium carboxylate ionic liquid lubricants of OFHC copper[J]. Wear,2013,303:495-509.
[8] RIVERA N,GARCÍA A,FERNÁNDEZ-GONZÁLEZ A,et al. Tribological behavior of three fatty acid ionic liquids in the lubrication of different material pairs[J]. Journal of Molecular Liquids,2019,296:111858-111869.
[9] ZHAI Wenzheng,LU Wenlong,LIU Xiaojun,et al. Nanodiamond as an effective additive in oil to dramatically reduce friction and wear for fretting steel/copper interfaces[J]. Tribology International,2019,129:75-81.
[10] 胡建军,赵雪,郭宁,等. 40Cr钢表面包埋渗Mo涂层组织及摩擦性能[J]. 中国表面工程,2021,34(1):60-69. HU Jianjun,ZHAO Xue,GUO Ning,et al. Microstructure and tribological properties of Mo-coating prepared by pack-cementation on 40Cr steel[J]. China Surface Engineering,2021,34(1):60-69.
[11] GULZAR M,MASJUKI H H,VARMAN M,et al. Improving the AW/EP ability of chemically modified palm oil by adding CuO and MoS₂ nanoparticles[J]. Tribology International,2015,88:271-279.
[12] 刘永强,张栋,李锋. 有机硅酸盐对45钢和灰铸铁HT150摩擦性能的影响[J]. 机械工程学报,2006,42(4):236-238. LIU Yongqiang,ZHANG Dong,LI Feng. Effects of organic silicate on the friction performance of 45 steel/HT150 pair[J]. Journal of Mechanical Engineering,2006,42(4):236-238.
[13] 尹艳丽,于鹤龙,王红美,等. 蛇纹石矿物作为润滑油添加剂对锡青铜摩擦学行为的影响[J]. 摩擦学学报,2020,40(4):516-525. YIN Yanli,YU Helong,WANG Hongmei,et al. Effect of serpentine mineral as a lubricant additive on the tribological behaviors of tin bronze[J]. Tribology,2020,40(4):516-525.
[14] YIN Yanli,YU Helong,WANG Hongmei,et al. Friction and wear behaviors of steel/bronze tribopairs lubricated by oil with serpentine natural mineral additive[J]. Wear,2020,456-457:203387.
[15] 张保森. 基于亚稳态蛇纹石矿物的自修复材料制备及摩擦学机理研究[D]. 上海:上海交通大学,2011. ZHANG Baosen. Preparation of self-reconditioning materials based on metastable serpentine mineral and investigation on their tribology mechanisms[D]. Shang hai:Shanghai Jiao Tong University,2011.
[16] 王利民. 纳米凹凸棒石的摩擦学性能及自修复机理研究[D]. 哈尔滨:哈尔滨工程大学,2015. WANG Limin. The research on tribological properties and self-reconditioning mechanics of nano-attapulgite[D]. Harbin:Harbin Engineering University,2015.
[17] JIA Xiaohua,HUANG Jian,LI Yong,et al. Monodisperse Cu nanoparticles@MoS₂ nanosheets as a lubricant additive for improved tribological properties[J]. Applied Surface Science,2019,494:430-439.
[18] NAN Feng,XU Yi,XU Binshi,et al. Effect of Cu nanoparticles on the tribological performance of attapulgite base grease[J]. Tribology Transactions,2015,58:1031-1038.
[19] 吴雪梅,周元康,杨绿,等. 纳米坡缕石/铜复合材料对钢球摩擦副的摩擦学性能[J]. 复合材料学报,2014,2(31):441-447. WU Xuemei,ZHOU Yuankang,YANG Lü,et al. Tribological properties of nano-palygorskite/copper composites as lubricant additive to steel ball tripair[J]. Acta Materiae Compositae Sinica,2014,2(31):441-447.
[20] ZHANG Baosen,XU Binshi,XU Yi,et al. Cu nanoparticles effect on the tribological properties of hydrosilicate powders as lubricant additive for steel-steel contacts[J]. Tribology International,2011,44:878-886.
[21] 杨育林,闻艳红,张瑞军,等. 磨损时间对金属磨损自修复的影响及机理分析[J]. 机械工程学报,2008,10(44):172-176. YANG Yulin,WEN Yanhong,ZHANG Ruijun,et al. Influence of wear time on metal wear self-repair and mechanism analysis[J]. Journal of Mechanical Engineering,2008,10(44):172-176.
[22] 张翼东,闫加省,孙磊,等. 纳米铜润滑油添加剂减摩抗磨及自修复性能[J]. 机械工程学报,2010,46(5):75-79. ZHANG Jidong,YAN Jiasheng,SUN Lei,et al. Friction reducing anti-wear and self-repairing properties of nano-Cu additive in lubricating oil[J]. Journal of Mechanical Engineering,2010,46(5):75-79.
[23] 韩云燕,乔旦,张霖,等. 膦酸酯类离子液体作为钢/铜锡合金润滑剂的摩擦学性能及其机理研究[J]. 摩擦学学报,2015,35(2):161-165. HAN Yunyan,QIAO Dan,ZHANG Lin,et al. Tribological performance and mechanism of phosphonate ionic liquids as lubricants for steel/tin bronze contact[J]. Tribology,2015,35(2):161-165.
[24] 葛翔宇,夏延秋,冯欣,等. 锂盐型电力复合脂的导电性和摩擦学性能[J]. 机械工程学报,2015,15(51):61-66. GE Xiangyu,XIA Yanqiu,FENG Xin,et al. Electrical conductivities and tribological properties of lithium salts conductive grease[J]. Journal of Mechanical Engineering,2015,15(51):61-66.
[25] 欧阳平,陈国需,张贤明,等. 点/线/面接触条件下喹唑啉酮胺润滑油添加剂的摩擦学性能[J]. 机械工程学报,2012,48(7):119-123. OUYANG Ping,CHEN Guoxu,ZHANG Xianming,et al. Tribological properties of quinazolinone amine as lubricating oil additive in point/line/surface contact condition[J]. Journal of Mechanical Engineering,2012,48(7):119-123.
[26] WAGNER C D,RIGGS W M,DAVIS L E,et al. Handbook of X-ray photoelectron spectroscopy[M]. Eden Prairie:Perkin-Elmer Corporation,1979.
[27] YAMASHITA T,HAYES P. Analysis of XPS spectra of Fe²⁺ and Fe³⁺ ions in oxide materials[J]. Applied Surface Science,2008(254):2441-2449.
[28] 刘浩,施杰,张泽,等. α-(Al,Cr,Fe)₂O₃相稳定性和力学性能的第一性原理计算[J].中国表面工程,2021,34(2):122-130.LIU Hao,SHI Jie,ZHANG Ze,et al. Phase stability andmechanical properties of α-(Al,Cr,Fe)₂O₃ phase byfirst-principles calculation[J].China Surface Engineering,2021,34(2):122-130.
[29] PELISSIER B,FONTAINE H,BEAURAIN A,et al. HF contamination of 200 mm Al wafers:A parallel angle resolved XPS study[J]. Microelectron Engineering, 2011(88):861-866.
[30] MONTESDEOCA-SANTANA A,JIMÉNEZ-RODRÍGUEZ E,MARRERO N,et al. XPS characterization of different thermal treatments in the ITO-Si interface of a carbonate-textured monocrystalline silicon solar cell[J]. Nuclear Instruments and Methods in Physics Research Section B,2010,268:374-378.
[31] 燕赵福. 微纳米蛇纹石矿物粉体的摩擦行为及其成膜机理研究[D]. 北京:中国地质大学,2014. YAN Zhaofu. Tribological properties of serpentine micro-nanoparticles and mechanism of tribofilm formation[D]. Beijing:China University of Geosciences,2014.
[32] 张博. 基于纳米凹凸棒石的在线修复型润滑脂制备与摩擦学机理研究[D]. 北京:装甲兵工程学院,2012. ZHANG Bo. Preparation of self-repairing greases based on nano attapulgite powders and investigation on their tribological characteristics[D]. Beijing:Academy of Armored Forces Engineering,2012.
[33] ZHANG Baosen,XU Yi,GAO Fei,et al. Sliding friction and wear behaviors of surface-coated natural serpentine mineral powders as lubricant additive[J]. Applied Surface Science,2011,257:2540-2549.
[34] NAN Feng,XU Yi,XU Binshi,et al. Effect of natural attapulgite powders as lubrication additive on the friction and wear performance of a steel tribo-pair[J]. Applied Surface Science,2014,307:86-91.
[35] 杨峰,夏晓雷,徐创. 纳米铜润滑油添加剂的摩擦学特性及其自修复机理[J]. 材料保护,2018,51(2):22-25. YANG Feng,XIA Xiaolei,XU Chuang. Self-repairing mechanism and tribological properties of nano-Cu as lubricating oil additives[J]. Mzterial Protection,2018,51(2):22-25.
[36] ZHANG Yawen,LI Zhipeng,YAN Jincan,et al. Tribological behaviours of surface-modified serpentine powder as lubricant additive[J]. Industrial Lubrication and Tribology,2016,68(1):1-8.
[37] CAO Zhengfeng,XIA Yanqiu,XI Xiang. Nano-montmorillonite-doped lubricating grease exhibiting excellent insulating and tribological properties[J]. Friction,2017,5:219-230.
[38] QI Xiaowei,LU Ling,JIA Zhining,et al. Comparative tribological properties of magnesium hexasilicate and serpentine powder as lubricating oil additives under high temperature[J]. Tribology International,2012,49:53-57.
[39] 许一,张保森,徐滨士,等. 镧/蛇纹石复合润滑材料的热力学及摩擦学性能[J]. 粉末冶金材料科学与工程,2011,16(3):349-354. XU Yi,ZHANG Baosen,XU Binshi,et al. Thermodynamic characteristics and tribological properties of lanthanum/serpentine composite lubricating material[J]. Materials Science and Engineering of Powder Metallurgy,2011,16(3):349-354.
[40] 尹艳丽,于鹤龙,王红美,等. 不同结构层状硅酸盐矿物作为润滑油添加剂的摩擦学性能[J]. 硅酸盐学报,2020,48(2):299-308. YIN Yanli,YU Helong,WANG Hongmei,et al. Tribological performance of phyllosilicate minerals as lubricating oil additives[J]. Journal of the Chinese Ceramic Society,2020,48(2):299-308.
[41] NAN Feng,XU Yi,XU Binshi,et al. Tribological behaviors and wear mechanisms of ultrafine magnesium aluminum silicate powders as lubricant additive[J]. Tribology International,2015,81:199-208.
[42] YU Helong,XU Yi,SHI Peijing,et al. Effect of thermal
activation on the tribological behaviours of serpentine ultrafine powders as an additive in liquid paraffin[J]. Tribology International,2011,44:1736-1741.

蛇纹石/纳米铜复合添加剂改善铜合金减摩抗磨性能的研究

Effect of Serpentine/Nano-Cu Composites as Lubricant Additive on Tribological Properties of Tin Bronze

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王伟, 魏春艳, 屈怡珅, 董少文, 吕凡凡, 金杰, 王快社. 黑磷烯量子点作为水基润滑添加剂的摩擦学性能研究[J]. 机械工程学报, 2024, 60(3): 226-237.
[2]	黄海军, 周敏波, 吴雪, 张新平. 芯片互连用粒径双峰分布纳米铜膏的低温无压烧结纳连接机理和接头可靠性[J]. 机械工程学报, 2022, 58(2): 58-65.
[3]	黄圆, 杭春进, 田艳红, 王晨曦, 张贺. 纳米铜银核壳焊膏脉冲电流快速烧结连接铜基板研究[J]. 机械工程学报, 2019, 55(24): 51-56.
[4]	秦红玲, 郭文涛, 李雪飞, 赵新泽, 徐翔. 闸门底枢摩擦副QT600-3/40Cr摩擦学性能及磨损表面功率谱密度表征[J]. 机械工程学报, 2019, 55(17): 102-109.
[5]	黎海旭, 唐鹏, 吴正涛, 代伟, 王启民, 祁正兵. TiSiN/AlCrN纳米多层涂层高温热稳定性及摩擦学特性研究[J]. 机械工程学报, 2018, 54(6): 32-40.
[6]	马国政, 雍青松, 王海斗, 何鹏飞, 徐滨士. 调制周期对纳米多层类石墨薄膜力学性能及摩擦学性能的影响[J]. 机械工程学报, 2018, 54(15): 92-99.
[7]	肖华平, 刘书海, 陈瑜, 王德国. 4种轴承钢在水基泥浆中摩擦学性能研究[J]. 机械工程学报, 2018, 54(13): 153-158.
[8]	马浩, 高殿荣, 毋少峰, 梁瑛娜. 水压马达仿生非光滑表面配流副摩擦磨损研究[J]. 机械工程学报, 2018, 54(13): 142-152.
[9]	顾军, 张朝辉, 黄宝成, 王磊, 李宽宽. 丙二醇无规共聚醚水溶液的摩擦学性能研究[J]. 机械工程学报, 2018, 54(1): 144-149.
[10]	黄圆, 田艳红, 江智, 王晨曦. 脉冲电流快速烧结纳米铜焊膏连接铜镍基板研究^*[J]. 机械工程学报, 2017, 53(4): 34-42.
[11]	李星亮, 岳文, 黄飞, 康嘉杰, 付志强. 磨料粒度对表面微织构纯钛干摩擦性能的影响[J]. 机械工程学报, 2017, 53(24): 25-33.
[12]	雍青松, 王海斗, 徐滨士, 马国政. 类金刚石薄膜摩擦机理及其摩擦学性能影响因素的研究现状[J]. 机械工程学报, 2016, 52(11): 95-107.
[13]	李楠楠, 康嘉杰, 王海斗, 董天顺, 许中林, 李国禄. 喷涂功率对NiCr-Cr3C2涂层表面自由能及其摩擦性能的影响[J]. 机械工程学报, 2015, 51(23): 96-102.
[14]	欧阳平;陈国需;张贤明;梁新元;李华锋. 点/线/面接触条件下喹唑啉酮胺润滑油添加剂的摩擦学性能[J]. , 2012, 48(7): 119-124.
[15]	王松;岳文;王成彪;高晓成;卜宏利;刘家浚. 渗氮GCr15钢在含氮硼酸酯添加剂润滑油作用下的摩擦学性能[J]. , 2012, 48(19): 128-133.