高固/低粘光固化陶瓷浆料制备与性能研究

doi:10.3901/JME.260084

机械工程学报 ›› 2026, Vol. 62 ›› Issue (3): 260-270.doi: 10.3901/JME.260084

• 特邀专栏：增材制造技术 • 上一篇

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高固/低粘光固化陶瓷浆料制备与性能研究

黄传真^1,2, 张仁凯^1,3, 王真^1,2, 徐龙华¹, 黄水泉¹, 曲美娜¹, 许征凯¹, 张迪嘉¹, 郭保苏¹, 靳田野¹, 王晓丹¹

1. 燕山大学机械工程学院秦皇岛 066004;
2. 燕山大学起重机械关键技术全国重点实验室秦皇岛 066004;
3. 潍柴雷沃智慧农业科技股份有限公司潍坊 261206

修回日期:2025-07-28 接受日期:2025-11-11 发布日期:2026-03-25
作者简介:黄传真(通信作者),男,1966年出生,博士,教授,博士研究生导师,国家级高层次人才。主要研究方向为增材制造、高效精密加工与刀具。E-mail:huangchuanzhen@ysu.edu.cn

Research on Preparation and Properties of Ceramic Slurries with High Solid Content/low Viscosity

HUANG Chuanzhen^1,2, ZHANG Renkai^1,3, WANG Zhen^1,2, XU Longhua¹, HUANG Shuiquan¹, QU Meina¹, XU Zhengkai¹, ZHANG Dijia¹, GUO Baosu¹, JIN Tianye¹, WANG Xiaodan¹

1. School of Mechanical Engineering, Yanshan University, Qinhuangdao 066004;
2. State Key Laboratory of Crane Technology, Yanshan University, Qinhuangdao 066004;
3. Weichai Lovol Intelligent Agriculture Technology Co., Ltd., Weifang 261206

Revised:2025-07-28 Accepted:2025-11-11 Published:2026-03-25
Supported by:
国家重点研发计划资助项目(2022YFB4601401,2022YFB4601400)。

摘要/Abstract

摘要： 随着增材制造技术在陶瓷材料制备领域的快速应用，开发具有高固相含量、低黏度的光固化陶瓷浆料成为多种陶瓷材料复杂结构增材制造的关键内容。以Si₃N₄基陶瓷复合材料为对象，系统研究高固/低粘多元复相陶瓷浆料的制备与性能优化。概述了浆料体系的设计思路，包括树脂基体配方、颗粒级配策略和添加剂优化：设计HDDA、TMPTA、ACMO与EA混合树脂(质量比1:1:1:1)；采用陶瓷颗粒粒径级配策略(颗粒质量比1 μm:0.5 μm:50 nm=0.17:0.67:0.16)；优化硅烷偶联剂KH560含量(质量分数为陶瓷颗粒总质量的5%)、分散剂BYK110含量(质量分数为陶瓷颗粒总质量的4%)、稀释剂NMP含量(质量分数为树脂质量的20%)。最终实现浆料流变性和可打印性全面提升，在55.56%固相含量下浆料黏度0.79 Pa·s、触变性553.1 Pa/s、屈服应力28.9 Pa；KH560、BYK110和NMP的添加，使浆料固相含量达到74%时，黏度降至3.87 Pa·s。本研究为高性能陶瓷零件增材制造适用浆料的制备提供了理论与技术支撑。

关键词: 光固化陶瓷, 表面改性, 高固相含量, 低黏度

Abstract: With the rapid application of additive manufacturing technology in the field of ceramic material fabrication, the development of light cured ceramic slurries with high solid content and low viscosity has become a key content in the complex structure additive manufacturing of various ceramic materials. This article focuses on Si₃N₄ based ceramic composite materials and studies high solid content/low viscosity multiphase ceramic slurries that meet the requirements of photopolymerization additive manufacturing, providing theoretical and technical support for the additive manufacturing of high-performance ceramic parts. The design concept of the slurry system is outlined, including the resin matrix formulation, particle grading strategy, and additive optimization. A composite resin matrix is designed and prepared by mixing the monomer resins HDDA, TMPTA, ACMO, and EA in a mass ratio of 1:1:1:1. A ceramic particle size grading strategy is adopted (particle mass ratio of 1 μm : 0.5 μm : 50 nm = 0.17 : 0.67 : 0.16). The contents of the silane coupling agent KH560 (5% of the total ceramic particle mass), dispersant BYK110 (4% of the total ceramic particle mass), and diluent NMP (20% of the resin mass) are optimized. This ultimately achieved comprehensive improvement in the slurry's rheological properties and printability. At a solid loading of 55.56%, the slurry exhibited a viscosity of 0.79 Pa·s, thixotropy of 553.1 Pa/s, and yield stress of 28.9 Pa. The addition of KH560, BYK110, and NMP reduced the slurry viscosity to 3.87 Pa·s even when the solid loading reached 74 wt%. This study provides theoretical and technical support for the preparation of applicable slurries used in additive manufacturing of high-performance ceramic components.

Key words: light cured ceramics, surface modification, high solid content, low viscosity

中图分类号:

TH164

黄传真, 张仁凯, 王真, 徐龙华, 黄水泉, 曲美娜, 许征凯, 张迪嘉, 郭保苏, 靳田野, 王晓丹. 高固/低粘光固化陶瓷浆料制备与性能研究[J]. 机械工程学报, 2026, 62(3): 260-270.

HUANG Chuanzhen, ZHANG Renkai, WANG Zhen, XU Longhua, HUANG Shuiquan, QU Meina, XU Zhengkai, ZHANG Dijia, GUO Baosu, JIN Tianye, WANG Xiaodan. Research on Preparation and Properties of Ceramic Slurries with High Solid Content/low Viscosity[J]. Journal of Mechanical Engineering, 2026, 62(3): 260-270.

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高固/低粘光固化陶瓷浆料制备与性能研究

Research on Preparation and Properties of Ceramic Slurries with High Solid Content/low Viscosity

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