黑磷烯量子点作为水基润滑添加剂的摩擦学性能研究

doi:10.3901/JME.2024.03.226

机械工程学报 ›› 2024, Vol. 60 ›› Issue (3): 226-237.doi: 10.3901/JME.2024.03.226

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黑磷烯量子点作为水基润滑添加剂的摩擦学性能研究

王伟¹, 魏春艳¹, 屈怡珅², 董少文¹, 吕凡凡¹, 金杰³, 王快社¹

1. 西安建筑科技大学冶金工程学院西安 710055;
2. 北京交通大学经济管理学院北京 100040;
3. 北京交通大学机械与电子控制工程学院北京 100040

收稿日期:2023-02-09 修回日期:2023-10-11 出版日期:2024-02-05 发布日期:2024-04-28
通讯作者: 王伟,男,1985年出生,博士,副教授,博士研究生导师。主要研究方向为润滑添加剂、液体超滑。E-mail:gackmol@163.com
作者简介:魏春艳,女, 1998 年出生,硕士研究生。主要研究方向为黑磷润滑。E-mail:wcyycw12@163.com
基金资助:
国家自然科学基金(51975450)、陕西省青年科技新星(2021KJXX-32)和西安市先进制造业技术攻关(21XJZZ0031)资助项目。

Tribological Properties of Black Phosphorus Quantum Dots as Water-based Lubrication Additive

WANG Wei¹, WEI Chunyan¹, QU Yishen², DONG Shaowen¹, LÜ Fanfan¹, JIN Jie³, WANG Kuaishe¹

1. School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055;
2. School of Economics and Management, Beijing Jiaotong University, Beijing 100040;
3. School of Mechanical, Electronic and Control Engineering Beijing Jiaotong University, Beijing 100040

Received:2023-02-09 Revised:2023-10-11 Online:2024-02-05 Published:2024-04-28

摘要/Abstract

摘要： 为了提高钛合金加工的表面质量,降低其加工成本。利用具有高承载、低摩擦等特性的黑磷烯量子点作为钛合金加工液的高效润滑介质。采用 MS-T3001 摩擦磨损试验机,以 GCr15 轴承钢/TC4 钛合金盘为摩擦副研究黑磷烯量子点作为水基润滑添加剂的摩擦学性能。试验结果表明,黑磷烯量子点的平均横向尺寸为 4.44 nm±0.86 nm,厚度约小于 4 nm,在超纯水中表现出良好的分散性。随着接触压力增加,摩擦因数和磨损率先快速减小后缓慢增加。在 1 273 MPa 接触压力、119.3 mg/L浓度下,和超纯水相比,黑磷烯量子点水基润滑添加剂的平均摩擦因数和磨损率分别降低 27.6 %和 28.29 %。磨痕表面分析表明,黑磷烯量子点水基润滑添加剂的抗磨减摩机理为钛合金磨损表面生成的 Fe₂O₃、TiO₂、Al₂O₃ 氧化物组成的摩擦化学反应膜及黑磷烯量子点层间剪切和滚珠效应的协同作用。此研究为黑磷烯水基润滑添加剂在钛合金切削润滑领域的应用提供理论依据。

关键词: 黑磷烯量子点, 润滑添加剂, 摩擦学性能, 润滑机理

Abstract: In order to improve the surface quality of titanium alloy processing and reduce its processing cost. Black phosphorus quantum dots(BPQDS) which have the advantages of higher bearing capacity and lower friction are used as the efficient lubrication medium for titanium alloy processing fluid. Using MS-T3001 friction and wear tester, the tribological properties of BPQDS as water-based lubrication additive are studied with GCr15/TC4 as frictional pair. The experimental results show that the average transverse size and the thickness of BPQDS are 4.44 nm±0.86 nm and less than 4 nm, respectively. BPQDS are presented the excellent dispersion stability in the ultrapure water. With the increase of contact pressure, the coefficient of friction (COF) and wear rate are decreased rapidly and then increased slowly. At the contact press of 1 273 MPa and the content of 119.3 mg/L, the average COF and wear rate of BPQDS as water-based lubrication additive are decreased by 27.6 % and 28.29 % respectively compared with ultra-pure water. The analysis of the worn surface find that the anti-wear and antifriction mechanism of BPQDS as water-based lubrication additive is the friction chemical reaction film composed of Fe₂O₃, TiO₂, Al₂O₃ oxides formed on the worn surface of titanium alloy and the synergism of the interlaminar shear and ball effect of the BPQDS. The research results provide a theoretical basis for the industrial application of black phosphorus as water-based lubrication additive in the field of titanium alloy cutting lubrication.

Key words: black phosphorus quantum dots, lubricantion additive, tribological properties, lubrication mechanism

中图分类号:

TH117

王伟, 魏春艳, 屈怡珅, 董少文, 吕凡凡, 金杰, 王快社. 黑磷烯量子点作为水基润滑添加剂的摩擦学性能研究[J]. 机械工程学报, 2024, 60(3): 226-237.

WANG Wei, WEI Chunyan, QU Yishen, DONG Shaowen, LÜ Fanfan, JIN Jie, WANG Kuaishe. Tribological Properties of Black Phosphorus Quantum Dots as Water-based Lubrication Additive[J]. Journal of Mechanical Engineering, 2024, 60(3): 226-237.

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黑磷烯量子点作为水基润滑添加剂的摩擦学性能研究

Tribological Properties of Black Phosphorus Quantum Dots as Water-based Lubrication Additive

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