• CN:11-2187/TH
  • ISSN:0577-6686

›› 2007, Vol. 43 ›› Issue (5): 194-198.

• 论文 • 上一篇    下一篇

纳米Al2O3/PS复合材料选区激光烧结成形域及力学性能

郑海忠;张坚;徐志锋   

  1. 南昌航空工业学院材料科学与工程学院;南京航空航天大学材料科学与技术学院
  • 发布日期:2007-05-15

SHAPING PARAMETRIC REGION AND MECHANICAL PROPERTIES OF SELECTIVE LASER SINTERING OF NANO-Al2O3/POLYSTYRENE COMPOSITE

ZHENG Haizhong;ZHANG Jian;XU Zhifeng   

  1. School of Materials Science and Engineering, Nanchang Institute of Aeronautical Technology School of Materials Science and Technology, Nanjing University of Aeronautics & Astronaut
  • Published:2007-05-15

摘要: 在前期研究确认激光功率P和扫描速度v对成形粉末NH1的选区激光烧结(Selective laser sintering, SLS)成形性具有显著性影响的基础上,重点研究P和v对NH1粉末的SLS成形性的影响,研究发现当P较小、v较快时,SLS烧结件结构不致密,强度较低;当P较高、v较慢时,SLS试件容易着火和翘曲变形;只有合理匹配P和v (即处在成形区内),才能直接制备出变形较小、密度较高的烧结件。同时对相同工艺条件下的Al2O3/PS纳米复合材料与纯聚苯乙烯SLS试件的缺口冲击吸收功进行比较,结果表明纳米复合材料的缺口冲击吸收功提高20%~50%,其最大值达到10.5 kJ/m2。利用场发射扫描式电子显微镜(FE-SEM)对NH1和纯PS(Polystyrene)粉SLS试件的断面进行微观结构分析,结果表明核壳式纳米Al2O3/PS复合粒子改善纳米氧化铝表面与聚苯乙烯极性的差异,纳米Al2O3在基体中分散性良好,且很好地起着增强增韧的效果。

关键词: 成形参数域, 聚合物基纳米复合材料, 缺口冲击吸收功, 选区激光烧结, 制备

Abstract: Based on the previous study in which laser power P and scan speed v have significant influences on the shaping performance of the powder NH1, the combined influences of laser power and scan speed are investigated. It is found that the physical density and strength of the specimens are little when P is low and v is fast; and smoke and warp distortion are observed when the specimens are sintered under high P and v speed; And the compact specimens with no warp distortion could be suc-cessfully fabricated under the appropriate combination of P and v which are in the proper forming shaping parametric region. The notched impact toughness of the sintered specimens is compared between the neat polystyrene powder and the power NH1 at the same process conditions. The result shows the notched impact toughness of nano-composite specimen is up to 10.5 kJ/m2 and it is 20%~50% higher than that of the neat polystyrene specimen. The FE-SEM micrograph of the speci-men’s section shows that the nano-particles disperse in matrix well and the polystyrene is toughened and strengthened because the polarity of nano-Al2O3 is modified by the nano-Al2O3/PS composite particles with core-shell.

Key words: Forming, Notched impact strength, Polymer matrix nanocomposite, Selective laser sintering(SLS), Shaping parametric region

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