• CN:11-2187/TH
  • ISSN:0577-6686

›› 2006, Vol. 42 ›› Issue (7): 46-50.

• 论文 • 上一篇    下一篇

提高拉伸条件下的钛合金高温抗氧化性

崔丽;栗卓新;魏琪   

  1. 北京工业大学材料科学与工程学院
  • 发布日期:2006-07-15

IMPROVEMENT ON RESISTANCE TO HIGH TEMPERATURE OXIDATION OF TITANIUM ALLOYS DURING TENSILE TEST

CUI Li;LI Zhuoxin;WEI Qi   

  1. College of Materials Science and Engineering, Beijing University of Technology
  • Published:2006-07-15

摘要: 钛合金高温成形时氧化问题严重影响产品的质量,采用有效的表面涂层防护是解决这一问题的重要途径,而目前的多种防护涂层都存在一些问题。因此选择锆英石粉末在TC4钛合金(Ti6Al4V)表面进行等离子喷涂,并对TC4合金在高温条件下氧化过程以及涂层对材料超塑性能的影响进行研究。在800 ℃、850 ℃及900 ℃温度条件下,对有氧化锆涂层和无涂层的试样以0.000 1 s-1,0.001 s-1,0.01 s-1和0.1s-1的应变速率进行拉伸试验。高温氧化时,无涂层的试样表面被氧化生成了氧化膜,XRD及EDS分析表明,氧化膜主要由TiO2组成,氧化温度和时间决定了膜的厚度。在有涂层保护的试样上,未发现该种氧化膜。在所有温度及应变速率下,有涂层试样的断面收缩率均比无涂层试样的断面收缩率有较大提高,且两种试样断面收缩率差距大小随试验温度和应变速率变化而变化,而抗拉强度和屈服强度并没有太大改变。但是,涂层本身由于塑性差,氧化锆涂层在拉伸过程后期涂层表面也会产生裂纹。

关键词: 高温抗氧化性, 拉伸试验, 钛合金, 氧化锆涂层

Abstract: Oxidation of the Ti6Al4V alloy at high temperature is a problem for the sound products. In order to protect the alloy from oxidation, surface coating method has been attempted and several coating materials has been investigated. A zircon coating is applied to the surface of Ti6Al4V alloy by plasma spray and the effect of coating on the superplasticity of the alloy as well as the oxidation behavior of the oxidation are studied. Uniaxial tensile tests are conducted at 800 ℃, 850 ℃ and 900 ℃ with an initial strain rate of 0.000 1 s–1, 0.00 1 s–1, 0.01 s–1 and 0.1 s–1. Studies show that an oxide film is formed on the surface of Ti6Al4V alloy and no such oxide film is found in the coated specimens. XRD and EDX analysis indicate that this oxide film mainly consists of TiO2. The thickness of the oxide film increases with increasing temperature and exposure time. Studies show that the elongations of the coated specimens are higher than those of the uncoated ones, while the ultimate strength and yield strength of the alloy are not changed. The difference in elongation between the coated and uncoated specimens is influenced by the temperature and initial strain rate. However, studies also show that there are some clefts formed on the coating layers at the later stage of deformation due to the brittle nature of the coating layers.

Key words: High temperature oxidation resistance, Tensile test, Titanium alloys, Zirconia coating

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