锂离子电池充放电机械压力特性研究

doi:10.3901/JME.2022.20.410

机械工程学报 ›› 2022, Vol. 58 ›› Issue (20): 410-420.doi: 10.3901/JME.2022.20.410

扫码分享

锂离子电池充放电机械压力特性研究

洪琰¹, 周龙¹, 张俊¹, 李相俊², 汪湘晋³, 马瑜涵³, 郑岳久¹

1. 上海理工大学机械工程学院上海 200082;
2. 中国电力科学研究院有限公司北京 100192;
3. 国网浙江省电力有限公司电力科学研究院杭州 310014

收稿日期:2021-09-15 修回日期:2021-12-30 出版日期:2022-10-20 发布日期:2022-12-27
通讯作者: 郑岳久(通信作者)，男，1986年出生，副教授，博士研究生导师。主要研究方向为新能源动力电池管理系统的集成、优化与控制。E-mail：yuejiu_zheng@163.com
作者简介:洪琰，男，1996年出生。主要研究方向为锂离子电池机械压力。E-mail：1427751182@qq.com
基金资助:
国家电网公司科技资助项目(3A-20-304-008)。

Study on Mechanical Pressure Characteristics of Charge and Discharge of Lithium-ion Battery

HONG Yan¹, ZHOU Long¹, ZHANG Jun¹, LI Xiangjun², WANG Xiangjin³, MA Yuhan³, ZHENG Yuejiu¹

1. Institute of Mechanical Engineering,University of Shanghai for Science and Technology, Shanghai 200082;
2. China Electric Power Research Institute, Beijing 100192;
3. State Grid Zhejiang Electric Power Research Institute, Hangzhou 310014

Received:2021-09-15 Revised:2021-12-30 Online:2022-10-20 Published:2022-12-27

摘要/Abstract

摘要： 软包锂离子电池在充放电期间因为锂离子的脱嵌使得电池表面产生形变进而形成机械压力。通过对软包锂离子电池施加一定预紧力后进行正常与滥用的充放电试验研究，揭示电池表面机械压力的变化特性规律。结果表明：在正常充电阶段，电池表面机械压力逐渐增大，在正常放电阶段，电池表面机械压力是一个逐渐恢复的过程；在滥用的过充电与过放电阶段，电池表面机械压力均表现出先缓慢增大后迅速增大(dF/dt>>0)的现象。针对过充电和过放电电池表面机械压力迅速增加的特点，进一步基于滥用特性提出锂离子电池热失控预警电压的确定方法和锂离子电池放电截止电压的确定方法，为软包锂离子电池的安全性设计和电池管理系统中过充电、过放电提供理论依据与方法指导。

关键词: 锂电池, 机械压力特性, 充放电, 过放电, 过充电

Abstract: During the charging and discharging of the soft-pack lithium-ion battery, the surface of the battery will deform due to the disembedding of lithium-ions, thus forming mechanical pressure. The normal and abuse charging-discharging experiments are carried out on the soft-pack lithium-ion battery after a certain preload applied, to reveal the change characteristics of the mechanical pressure on the battery surface.The results show that the surface mechanical pressure of the battery increases gradually during the normal charging stage, while the surface mechanical pressure of the battery recovers gradually during the normal discharging stage. In the over-charging and over-discharging stages of abuse, the surface mechanical pressure of the battery increases slowly at first and then rapidly (dF/dt>>0). In view of the rapid increase of mechanical pressure on the surface of over-charging and over-discharging batteries, the determination method of thermal runaway warning voltage and discharge cut-off voltage of lithium-ion batteries are further proposed based on the abuse characteristics,which will provide theoretical basis and method guidance for the safety design of soft-pack lithium-ion battery and the battery system management of overcharging and overdischarging.

Key words: lithium-ion batteries, mechanical pressure characteristics, charge and discharge, over-charge, over-discharg

中图分类号:

TM911

洪琰, 周龙, 张俊, 李相俊, 汪湘晋, 马瑜涵, 郑岳久. 锂离子电池充放电机械压力特性研究[J]. 机械工程学报, 2022, 58(20): 410-420.

HONG Yan, ZHOU Long, ZHANG Jun, LI Xiangjun, WANG Xiangjin, MA Yuhan, ZHENG Yuejiu. Study on Mechanical Pressure Characteristics of Charge and Discharge of Lithium-ion Battery[J]. Journal of Mechanical Engineering, 2022, 58(20): 410-420.

参考文献

[1] HAN Xuebing，LU Languang，ZHENG Yuejiu，et al. A review on the key issues of the lithium ion battery degradation among the whole life cycle[J]. eTransportation，2019，1(C):1-21.
[2] HANNAN M，LIPU M，HUSSAIN A，et al. A review of lithium-ion battery state of charge estimation and management system in electric vehicle applications:challenges and recommendations[J]. Renewable and Sustainable Energy Reviews，2017，1(78):834-854.
[3] LA Xueqin，WU Yinbo，LIAN Jie，et al. Energy management of hybrid electric vehicles:a review of energy optimization of fuel cell hybrid power system based on genetic algorithm[J]. Energy Conversion and Management，2020，205(C):205-226.
[4] FENG Xuning，OUYANG Minggao，LIU Xiang，et al. Thermal runaway mechanism of lithium ion battery for electric vehicles:A review[J]. Energy Storage Mater，2018，10:246-267.
[5] ZHOU Long，ZHENG Yuejiu，OUYANG Minggao，et al. A study on parameter variation effects on batterypacks for electric vehicles[J]. J. Power Sources，2017，364:242-252.
[6] 李哲，韩雪冰，卢兰光，等. 动力型磷酸铁锂电池的温度特性[J]. 机械工程学报，2011，47(18):115-120. LI Zhe，HAN Xuebing，LU Languang，et al. Temperature characteristics of power lithium iron phosphate batteries[J]. Journal of Mechanical Engineering，2011，47(18):115-120.
[7] 向兆军，胡凤玲，胡晓松. 基于电池组模型和聚类算法的锂离子电池组SOC不一致估计[J]. 机械工程学报，2020，56(18):154-163. XIANG Zhaojun，HU Fengling，HU Xiaosong. Inconsistent estimation of lithium-ion battery soc based on battery model and clustering algorithm[J]. Journal of Mechanical Engineering，2020，56(18):154-163.
[8] 汪宜秀，魏学哲，戴海峰. 面向整组寿命最大化的电动汽车电池一致性变化规律及其均衡策略[J]. 机械工程学报，2020，56(22):176-183. WANG Yixiu，WEI Xuezhe，DAI Haifeng. Consistency variation law and equalization strategy for electric vehicle batteries for the maximization of whole group life [J]. Journal of Mechanical Engineering，2020，56(22):176-183.
[9] 张鑫，李琰，王文斌，等. 电动汽车充电预约配对算法研究[J]. 电气工程学报，2020，15(2):18-23. ZHANG Xin，LI Yan，WANG Wenbin，et al. Research on the reservation matching algorithm for electric vehicles charging[J]. Journal of Electrical Engineering，2020，15(2):18-23.
[10] 冯仕杰，刘韬，潘萨，等. 基于分层优化的电动汽车有序充电策略[J]. 电气工程学报，2021，16(3):137-144. FENG Shijie，LIU Tao，PAN Sa，et al. Coordinated charging strategy for electric vehicles based on hierarchical optimization[J]. Journal of Electrical Engineering，2021，16(3):137-144.
[11] 张军，曾云路，邹舜章. 软包锂电池在适当压力下的膨胀及寿命研究[J]. 电源技术，2019，43(10):1641-1644. ZHANG Jun，ZENG Yunlu，ZOU Shunzhang. Research on expansion and life of soft packed lithium battery under appropriate pressure[J]. Power Sources，2019，43(10):1641-1644.
[12] MUSSA A，KLETT M，LINDBERGH G，et al. Effects of external pressure on the performance and ageing of single-layer lithium-ion pouch cells[J]. J. Power Sources，2018，385:18-26.
[13] CHOI Y，LIM H，SEO J，et al. Development of standardized battery pack for next-generation PHEVs in considering the effect of external pressure on lithium-ion pouch cells[J]. SAE Int. J. Alt. Power，2018，7:195-205.
[14] 张军，韩旭，胡春姣，等. 软包锂离子电池模块结构压力的优化[J]. 汽车工程，2016，38(6):669-673，715. ZHANG Jun，HAN Xu， HU Chunjiao，et al. Optimization of structural pressure of soft pack lithium-ion battery modules[J]. Automotive Engineering，2016，38(6):669-673，715.
[15] 崔锦，石川，赵金保. 机械压力对锂电池性能影响的研究进展[J]. 化工学报，2021，72(7):3511-3523. CUI Jin，SHI Chuan，ZHAO Jinbao. Mechanical stress on the research progress of lithium battery performance influence[J]. Journal of Chemical Industry，2021，72(7):3511-3523.
[16] JIANG Yihui，XU Jun，HOU Wenlong，et al. A stack pressure based equivalent mechanical model of lithium-ion pouch batteries[J]. Energy，2021，133:221.
[17] DAI Haifeng，YU Chenchen，WEI Xuezhe，et al. State of charge estimation for lithium-ion pouch batteries based on stress measurement[J]. Energy，2017，129:16-27.
[18] ZHOU Long，XING Licong，ZHENG Yuejiu，et al. A study of external surface pressure effects on the properties for lithium-ion pouch cells[J]. International Journal of Energy Research，2020，44(8):6778-6791.
[19] KOYAMA Y，MAKIMURA Y，OHZUKU T，et al. Crystal and electronic structures of super structural Li_1-x[Co_1/3Ni_1/3Mn_1/3]O₂(0≤x≤1)[J]. J. Power Sources，2003，119(121):644-648.
[20] 于臣臣，戴海峰. 锂离子单体电池应力测量与分析[J].机电一体化，2015，21(8):14-17，32. YU Chenchen，DAI Haifeng. Stress measurement and analysis of lithium ion battery[J]. Mechatronics，2015，21(8):14-17，32.
[21] 张青松，赵启臣. 商用钴酸锂电池过充电安全性研究[J]. 电源技术，2021，45(3):286-288，316. ZHANG Qingsong，ZHAO Qichen. Research on overcharge safety of commercial lithium cobalt batteries[J]. Chinese Journal of Power Sources，2021，45(3):286-288，316.
[22] 杨瑞鑫，熊瑞，孙逢春. 锂离子动力电池外部短路测试平台开发与试验分析[J]. 电气工程学报，2021，16(1):103-118. YANG Ruixin，XIONG Rui，SUN Fengchun. Experimental platform development and characteristics analysis of external short circuit in lithium-ion batteries[J]. Journal of Electrical Engineering，2021，16(1):103-118.
[23] 杜海忠，骆滔，宋浩谊，等. 基于电压平衡的锂电池主动均衡电路及策略[J]. 电气工程学报，2021，16(3):145-151. DU Haizhong，LUO Tao，SONG Haoyi，et al. Active balancing circuit and strategy of Li-ion battery based on voltage balance[J]. Journal of Electrical Engineering，2021，16(3):145-151.
[24] GUO Rui，LU Languang，OUYANG Minggao，et al. Mechanism of the entire over-discharge process and over-discharge-induced internal short circuit in lithium-ion batteries[J]. Scientific Reports，2016，6(1):359-367.

锂离子电池充放电机械压力特性研究

Study on Mechanical Pressure Characteristics of Charge and Discharge of Lithium-ion Battery

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	于全庆, 王灿, 李建明, 汤爱华, 赵立军. 多拓扑结构锂电池组外短路特性分析及模型评价[J]. 机械工程学报, 2023, 59(6): 159-172.
[2]	高锋阳, 张浩然, 王文祥, 李明明. 规则控制与行驶工况相结合的现代有轨电车能量管理策略[J]. 机械工程学报, 2023, 59(4): 221-231.
[3]	邵嗣杨, 马翔, 袁伟, 张开宇, 傅晓飞, 黄晨宏. 含电动汽车的不确定性微电网鲁棒优化调度方法^*[J]. 电气工程学报, 2023, 18(2): 201-209.
[4]	李维聪, 穆浩, 沈恒龙, 于全庆. 固态锂电池在载运工具中的应用前景分析^*[J]. 电气工程学报, 2022, 17(4): 88-102.
[5]	刘王泽宇, 李青, 庾甜甜, 熊锦晨, 张洪源, 董明, 任明. 锂离子电池过放电状态的阻抗特性研究^*[J]. 电气工程学报, 2022, 17(4): 51-60.
[6]	于子轩, 孟国栋, 谢小军, 赵勇, 成永红. 磷酸铁锂储能电池过充热失控仿真研究^*[J]. 电气工程学报, 2022, 17(3): 30-39.
[7]	唐鑫, 欧阳权, 黄俍卉, 王志胜, 马瑞. 基于深度强化学习的锂电池快速充电控制策略[J]. 机械工程学报, 2022, 58(22): 69-78.
[8]	张云, 魏逸航, 刘强强, 孔治国. 基于车载宽增益双向直流变换器的多源电动汽车充放电一体化方法[J]. 电气工程学报, 2022, 17(2): 101-109.
[9]	张朝龙, 赵筛筛, 何怡刚. 基于信息熵与PSO-LSTM的锂电池组健康状态估计方法[J]. 机械工程学报, 2022, 58(10): 180-190.
[10]	周洋捷, 王震坡, 洪吉超, 曲昌辉, 山彤欣, 张景涵, 侯岩凯. 新能源汽车动力电池“过充电-热失控”安全防控技术研究综述[J]. 机械工程学报, 2022, 58(10): 112-135.
[11]	熊瑞, 闫良基, 王榘. 功率需求驱动的电动载运装备用动力电池充放电能力预测方法[J]. 机械工程学报, 2021, 57(20): 161-171.
[12]	李志杰, 陈吉清, 兰凤崇, 周云郊. 方形锂离子电池内芯层集式模型方法及细观变形失效分析[J]. 机械工程学报, 2021, 57(18): 229-239.
[13]	王怀铷, 孙宜听, 金阳. 磷酸铁锂储能电池簇过充热失控蔓延特性仿真研究[J]. 机械工程学报, 2021, 57(14): 32-39.
[14]	方永旺,方红伟,刘乙彤. 基于开关磁阻电机的飞轮电池直流充放电控制[J]. 电气工程学报, 2016, 11(3): 28-33.
[15]	李徐佳, 高殿荣, 王华山. 锂电池极片干燥箱风刀内流特性的试验与数值模拟对比研究[J]. 机械工程学报, 2015, 51(24): 105-111.