激光诱导制造石墨烯研究现状与发展趋势

doi:10.3901/JME.2022.03.235

机械工程学报 ›› 2022, Vol. 58 ›› Issue (3): 235-250.doi: 10.3901/JME.2022.03.235

扫码分享

激光诱导制造石墨烯研究现状与发展趋势

蔺娜¹, 林志燃², 陈瀚宁¹, 陆龙生²

1. 天津工业大学机械工程学院天津 300392;
2. 华南理工大学机械与汽车工程学院广州 510640

收稿日期:2021-03-24 修回日期:2021-10-17 出版日期:2022-02-05 发布日期:2022-03-19
通讯作者: 陈瀚宁(通信作者),男,1979年生,博士,教授,博士研究生导师。主要研究方向为智能制造、先进制造技术。Email:183494284@qq.com
作者简介:蔺娜,女,1981年出生,博士研究生。主要研究方向为激光诱导石墨烯先进制造方法。E-mail:6381873@qq.com;林志燃,男,2000年出生。主要研究方向为激光制造技术。E-mail:linzhiran1225@163.com;陆龙生,男,1981年出生,博士,教授,硕士研究生导师。主要研究方向为表面功能结构先进制造。Email:meluls@scut.edu.cn
基金资助:
国家自然科学基金（51775197）和广东省自然科学基金（2018A050506007）资助项目。

Current Status of Research and Development Trend of Laser-induced Graphene Manufacturing

LIN Na¹, LIN Zhiran², CHEN Hanning¹, LU Longsheng²

1. School of Mechanical Engineering, Tianjin Polytechnic University, Tianjin 300392;
2. School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou 510640

Received:2021-03-24 Revised:2021-10-17 Online:2022-02-05 Published:2022-03-19

摘要/Abstract

摘要： 石墨烯作为备受关注的二维纳米材料，具备优异的机械强度、电导性和导热性，广泛应用于各个领域。传统的石墨烯制造技术存在高成本、低产率等问题，不利于石墨烯的工业化生产；近年来发展的激光诱导制造石墨烯技术具有工艺简单、成本低、产率高的优势，这使激光诱导成为石墨烯制造技术的热点。简要阐述了激光产生的机理，展开介绍了激光诱导石墨烯的前驱体种类并做出归纳，总结了激光诱导石墨烯的各类表征技术，重点阐述了激光诱导石墨烯的制造方法，并归纳分析各类因素对制造的影响，并介绍了其在各个领域的应用，最后讨论了目前激光诱导石墨烯的发展趋势。

关键词: 石墨烯, 激光, 二维材料

Abstract: As a two-dimensional nanomaterial that has attracted much attention, graphene has excellent mechanical strength, electrical conductivity and thermal conductivity, and is widely used in various fields. Traditional graphene manufacturing technology has problems such as high cost and low yield, which are not conducive to the industrial production of graphene. The laser-induced manufacturing graphene technology developed in recent years has the advantages of simple process, low cost and high yield, which makes laser become a hot spot in graphene manufacturing technology. This article briefly describes the mechanism of laser generation, introduces and summarizes the precursor types of laser-induced graphene, summarizes various characterization techniques of laser-induced graphene, and focuses on the manufacturing method of laser-induced graphene, and summarizes Analyze the influence of various factors on manufacturing, introduce its application in various fields, and finally discuss the current development trend of laser-induced graphene.

Key words: graphene, laser, two-dimensional material

中图分类号:

TH16

蔺娜, 林志燃, 陈瀚宁, 陆龙生. 激光诱导制造石墨烯研究现状与发展趋势[J]. 机械工程学报, 2022, 58(3): 235-250.

LIN Na, LIN Zhiran, CHEN Hanning, LU Longsheng. Current Status of Research and Development Trend of Laser-induced Graphene Manufacturing[J]. Journal of Mechanical Engineering, 2022, 58(3): 235-250.

参考文献

[1] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al. Electric field effect in atomically thin carbon films supplementary[J]. Science,2004,306(5696):666-669.
[2] OSHIMA C,NAGASHIMA A. Ultra-thin epitaxial films of graphite and hexagonal boron nitride on solid surfaces[J]. Journal of Physics Condensed Matter,1997,9(1):1-20.
[3] GEIM A K. Graphene:Status and prospects[J]. Science,2009,324(5934):1530-1535.
[4] REINA A,JIA Xiaoting,HO J,et al. Large area,few-layer graphene films on arbitrary substrates by chemical vapor deposition[J]. Nano Letters,2009,9(1):30-35.
[5] EL-KADY M F,STRONG V,DUBIN S,et al. Laser scribing of high-performance and flexible graphene-based electrochemical capacitors[J]. Science,2012,335(6074):1326-1330.
[6] LI Yilun,LUONG D X,ZHANG Jibo,et al. Laser-induced graphene in controlled atmospheres:from superhydrophilic to superhydrophobic surfaces[J]. Advanced Materials,2017,29(27):1700496-1700496-8.
[7] ZHU Jianxiong,CHO M,LI Yutao,et al. Biomimetic turbinate-like artificial nose for hydrogen detection based on 3D porous laser-induced graphene[J]. ACS Applied Materials and Interfaces,2019,11(27):24386-24394.
[8] XIE Yunchao,ZHANG Chi,HE Xiaoqing,et al. Monolithic electrochemical cells for overall water splitting[J]. Journal of Power Sources,2018,397:37-43.
[9] WANG Xuebin,ZHANG Yuanjian,ZHI Chunyi,et al. Three-dimensional strutted graphene grown by substrate-free sugar blowing for high-power-density supercapacitors[J]. Nature Communications,2013,4:3905-3905-8.
[10] BERGER C,SONG Zhimin,LI Tianbo,et al. Ultrathin epitaxial graphite:2D electron gas properties and a route toward graphene-based nanoelectronics[J]. Journal of Physical Chemistry B,2004,108(52):19912-19916.
[11] CAMBAZ Z G,YUSHIN G,OSSWALD S,et al. Noncatalytic synthesis of carbon nanotubes,graphene and graphite on SiC[J]. Carbon,2008,46(6):841-849.
[12] TRUSOVAS R,RAČIUKAITIS G,NIAURA G,et al. Recent advances in laser utilization in the chemical modification of graphene oxide and its applications[J]. Advanced Optical Materials,2016,4(1):37-65.
[13] 汤勇,刘辉龙,陆龙生,等. 激光加工平面型微超级电容器的研究进展与发展趋势[J]. 机械工程学报,2019,55(4):189-206. TANG Yong,LIU Huilong,LU Longsheng,et al. Research progress and perspective trend of laser-machined in-plane micro-supercapacitors[J]. Journal of Mechanical Engineering,2019,55(4):189-206.
[14] LIN Jian,PENG Zhiwei,LIU Yuanyue,et al. Laser-induced porous graphene films from commercial polymers[J]. Nature Communications,2014,5:6714-6714-8.
[15] YE Ruquan,CHYAN Y,ZHANG Jibo,et al. Laser-induced graphene formation on wood[J]. Advanced Materials,2017,29(37):1702211-1702211-7.
[16] WAN Xiangjian,HUANG Yi,CHEN Yongsheng. Focusing on energy and optoelectronic applications:A journey for graphene and graphene oxide at large scale[J]. Accounts of Chemical Research,2012,45(4):598-607.
[17] SINGH S P,LI Yilun,ZHANG Jibo,et al. Sulfur-doped laser-induced porous graphene derived from polysulfone-class polymers and membranes[J]. ACS Nano,2018,12(1):289-297.
[18] ZHANG Zhuchan,SONG Mengmeng,HAO Junxing,et al. Visible light laser-induced graphene from phenolic resin:A new approach for directly writing graphene-based electrochemical devices on various substrates[J]. Carbon,2018,127:287-296.
[19] SOPRONYI M,SIMA F,VAULOT C,et al. Direct synthesis of graphitic mesoporous carbon from green phenolic resins exposed to subsequent UV and IR laser irradiations[J]. Scientific Reports,2016,6:39617-39617-13.
[20] YE Ruquan,HAN Xiao,KOSYNKIN D V,et al. Laser-induced conversion of teflon into fluorinated nanodiamonds or fluorinated graphene[J]. ACS Nano,2018,12(2):1083-1088.
[21] SCHMIDT H,IHLEMANN J,WOLFF-ROTTKE B,et al. Ultraviolet laser ablation of polymers:Spot size,pulse duration,and plume attenuation effects explained[J]. Journal of Applied Physics,1998,83(10):5458-5468.
[22] CHYAN Y,YE Ruquan,LI Yilun,et al. Laser-induced graphene by multiple lasing:toward electronics on cloth,paper,and food[J]. ACS Nano,2018,12(3):2176-2183.
[23] LE T-S D,PARK S,AN Jianing,et al. Ultrafast laser pulses enable one-step graphene patterning on woods and leaves for green electronics[J]. Advanced Functional Materials,2019,29(33):1805271-1805271-8.
[24] ZHANG Wenli,LEI Yongjiu,MING Fangwang,et al. Lignin laser lithography:A direct-write method for fabricating 3D graphene electrodes for microsupercapacitors[J]. Advanced Energy Materials,2018,8(27):1801840-1801840-9.
[25] WANG Shutong,YU Yongchao,LUO Si,et al. All-solid-state supercapacitors from natural lignin-based composite film by laser direct writing[J]. Applied Physics Letters,2019,115(8):083904-083904-5.
[26] TRUSOVAS R,RATAUTAS K,RAČIUKAITIS G,et al. Graphene layer formation in pinewood by nanosecond and picosecond laser irradiation[J]. Applied Surface Science,2019,471:154-161.
[27] PRESSER V,HEON M,GOGOTSI Y. Carbide-derived carbons-from porous networks to nanotubes and graphene[J]. Advanced Functional Materials,2011,21(5):810-833.
[28] LEE S,TONEY M F,KO W,et al. Laser-synthesized epitaxial graphene[J]. ACS Nano,2010,4(12):7524-7530.
[29] YANNOPOULOS S N,SIOKOU A,NASIKAS N K,et al. CO₂-laser-induced growth of epitaxial graphene on 6H-SiC(0001)[J]. Advanced Functional Materials,2012,22(1):113-120.
[30] CHOI I,JEONG H Y,JUNG D Y,et al. Laser-induced solid-phase doped graphene[J]. ACS Nano,2014,8(8):7671-7677.
[31] VIROJANADARA C,SYVÄJARVI M,YAKIMOVA R,et al. Homogeneous large-area graphene layer growth on 6H-SiC(0001)[J]. Physical Review B-Condensed Matter and Materials Physics,2008,78(24):245403-245403-6.
[32] JIANG Juan,LIN Zhe,YE Xiaohui,et al. Graphene synthesis by laser-assisted chemical vapor deposition on Ni plate and the effect of process parameters on uniform graphene growth[J]. Thin Solid Films,2014,556:206-210.
[33] ZHU Chenguang,ZHAO Dongmei,WANG Kedian,et al. Direct laser writing of graphene films from a polyether ether ketone precursor[J]. Journal of Materials Science,2019,54(5):4192-4201.
[34] YE Jianglin,TAN Huabing,WU Shuilin,et al. Direct laser writing of graphene made from chemical vapor deposition for flexible,integratable micro-supercapacitors with ultrahigh power output[J]. Advanced Materials,2018,30(27):1801384-1801384-8.
[35] PARK J B,XIONG W,GAO Y,et al. Fast growth of graphene patterns by laser direct writing[J]. Applied Physics Letters,2011,98(12):123109-123109-3.
[36] GAVILLET J,LOISEAU A,JOURNET C,et al. Root-growth mechanism for single-wall carbon nanotubes[J]. Physical Review Letters,2001,87(27):275504-275504-4.
[37] PARK J B,XIONG W,XIE Z Q,et al. Transparent interconnections formed by rapid single-step fabrication of graphene patterns[J]. Applied Physics Letters,2011,99(5):053103-053103-3.
[38] HEMANI G K,VANDENBERGHE W G,BRENNAN B,et al. Interfacial graphene growth in the Ni/SiO₂ system using pulsed laser deposition[J]. Applied Physics Letters,2013,103(13):134102-134102-4.
[39] ZHANG Hongxin,FENG P X. Fabrication and characterization of few-layer graphene[J]. Carbon,2010,48(2):359-364.
[40] KOH A T T,FOONG Y M,CHUA D H C. Cooling rate and energy dependence of pulsed laser fabricated graphene on nickel at reduced temperature[J]. Applied Physics Letters,2010,97(11):114102-114102-3.
[41] YE Ruquan,JAMES D K,TOUR J M. Laser-induced graphene[J]. Accounts of Chemical Research,2018,51(7):1609-1620.
[42] WANG Yanan,WANG Yong,ZHANG Peipei,et al. Laser-induced freestanding graphene papers:A new route of scalable fabrication with tunable morphologies and properties for multifunctional devices and structures[J]. Small,2018,14(36):1802350-1802350-9.
[43] CLERICI F,FONTANA M,BIANCO S,et al. In situ MoS₂ decoration of laser-induced graphene as flexible supercapacitor electrodes[J]. ACS Applied Materials and Interfaces,2016,8(16):10459-10465.
[44] BISSETT M A,KINLOCH I A,DRYFE R A W. Characterization of MoS₂−graphene composites for highperformance coin cell supercapacitors[J]. ACS Applied Materials and Interfaces,2015,7(31):17388-17398.
[45] DENG Heng,ZHANG Chi,XIE Yunchao,et al. Laser induced MoS2/carbon hybrids for hydrogen evolution reaction catalysts[J]. Journal of Materials Chemistry A,2016,4(18):6824-6830.
[46] PENG Zhiwei,YE Ruquan,MANN J A,et al. Flexible boron-doped laser-induced graphene microsupercapacitors[J]. ACS Nano,2015,9(6):5868-5875.
[47] WANG Shujuan,JING Xinli,WANG Yong,et al. High char yield of aryl boron-containing phenolic resins:The effect of phenylboronic acid on the thermal stability and carbonization of phenolic resins[J]. Polymer Degradation and Stability,2014,99:1-11.
[48] GUPTA A,HOLOIDOVSKY L,THAMARAISELVAN C,et al. Silver-doped laser-induced graphene for potent surface antibacterial activity and anti-biofilm action[J]. Chemical Communications,2019,55(48):6890-6893.
[49] SONG Weixing,ZHU Jianxiong,GAN Baoheng,et al. Flexible,stretchable,and transparent planar microsupercapacitors based on 3d porous laser-induced graphene[J]. Small,2018,14(1):1702249-1702249-7.
[50] KOH A T T,FOONG Y M,CHUA D H C. Comparison of the mechanism of low defect few-layer graphene fabricated on different metals by pulsed laser deposition[J]. Diamond and Related Materials,2012,25:98-102.
[51] IN J B,HSIA B,YOO J H,et al. Facile fabrication of flexible all solid-state micro-supercapacitor by direct laser writing of porous carbon in polyimide[J]. Carbon,2015,83:144-151.
[52] PENG Zhiwei,LIN Jian,YE Ruquan,et al. Flexible and stackable laser-induced graphene supercapacitors[J]. ACS Applied Materials and Interfaces,2015,7(5):3414-3419.
[53] BASU A,ROY K,SHARMA N,et al. CO₂ laser direct written MOF-based metal-decorated and heteroatom-doped porous graphene for flexible all-solid-state microsupercapacitor with extremely high cycling stability[J]. ACS Applied Materials and Interfaces,2016,8(46):31841-31848.
[54] LI Lei,ZHANG Jibo,PENG Zhiwei,et al. High-performance pseudocapacitive microsupercapacitors from laser-induced graphene[J]. Advanced Materials,2016,28(5):838-845.
[55] YI Jingsi,CHEN Jiahua,YANG Zheng,et al. Facile patterning of laser-induced graphene with tailored Li nucleation kinetics for stable lithium-metal batteries[J]. Advanced Energy Materials,2019,9(38):1901796-1901796-11.
[56] ASLAM S,SAGAR R U R,LIU Yixin,et al. Graphene decorated polymeric flexible materials for lightweight high areal energy lithium-ion batteries[J]. Applied Materials Today,2019,17:123-129.
[57] REN Muqing,ZHANG Jibo,TOUR J M. Laser-induced graphene hybrid catalysts for rechargeable Zn-air batteries[J]. ACS Applied Energy Materials,2019,2(2):1460-1468.
[58] ZHANG Cheng,XIE Yunchao,DENG Heng,et al. Monolithic and flexible ZnS/SnO₂ ultraviolet photodetectors with lateral graphene electrodes[J]. Small,2017,13(18):1604197-1604197-7.
[59] YUAN Wenjing,SHI Gaoquan. Graphene-based gas sensors[J]. Journal of Materials Chemistry A,2013,1(35):10078-10091.
[60] DOSI M,LAU I,ZHUANG Yichen,et al. Ultrasensitive electrochemical methane sensors based on solid polymer electrolyte-infused laser-induced graphene[J]. ACS Applied Materials and Interfaces,2019,11(6):6166-6173.
[61] CHHETRY A,SHARIFUZZAMAN M,YOON H,et al. MoS₂-decorated laser-induced graphene for a highly sensitive,hysteresis-free,and reliable piezoresistive strain sensor[J]. ACS Applied Materials and Interfaces,2019,11(25):22531-22542.
[62] CARVALHO A F,FERNANDES A J S,LEITÃO C,et al. Laser-induced graphene strain sensors produced by ultraviolet irradiation of polyimide[J]. Advanced Functional Materials,2018,28(52):1805271-1805271-8.
[63] NAG A,MUKHOPADHYAY S C,KOSEL J. Sensing system for salinity testing using laser-induced graphene sensors[J]. Sensors and Actuators A:Physical,2017,264:107-116.
[64] ZHANG Jibo,ZHANG Chenhao,SHA Junwei,et al. Efficient water-splitting electrodes based on laser-induced graphene[J]. ACS Applied Materials and Interfaces,2017,9(32):26840-26847.
[65] LI Lihua,YU Lili,LIN Zhaoyong,et al. Reduced TiO₂-graphene oxide heterostructure as broad spectrum-driven efficient water-splitting photocatalysts[J]. ACS Applied Materials and Interfaces,2016,8(13):8536-8545.
[66] PERREAULT F,DE FARIA A F,NEJATI S,et al. Antimicrobial properties of graphene oxide nanosheets:Why size matters[J]. ACS Nano,2015,9(7):7226-7236.
[67] LIU Shaobin,ZENG T H,HOFMANN M,et al. Antibacterial activity of graphite,graphite oxide,graphene oxide,and reduced graphene oxide:Membrane and oxidative stress[J]. ACS Nano,2011,5(9):6971-6980.
[68] SINGH S P,LI Yilun,BE'ER A,et al. Laser-induced graphene layers and electrodes prevents microbial fouling and exerts antimicrobial action[J]. ACS Applied Materials and Interfaces,2017,9(21):18238-18247.
[69] THAKUR A K,SINGH S P,KLEINBERG M N,et al. Laser-induced graphene-PVA composites as robust electrically conductive water treatment membranes[J]. ACS Applied Materials and Interfaces,2019,11(11):10914-10921.
[70] RATHINAM K,SINGH S P,LI Yilun,et al. Polyimide derived laser-induced graphene as adsorbent for cationic and anionic dyes[J]. Carbon,2017,124:515-524.

激光诱导制造石墨烯研究现状与发展趋势

Current Status of Research and Development Trend of Laser-induced Graphene Manufacturing

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	吴淑晶, 王大中, 谷顾全, 黄帅, 董国军, 郭国强, 安庆龙, 李长河. 多种能场高性能加工复杂曲面关键技术研究进展[J]. 机械工程学报, 2024, 60(9): 152-167.
[2]	温秋玲, 杨野, 黄辉, 黄国钦, 胡中伟, 陈金鸿, 汪晖, 吴贤. 激光复合加工硬脆性材料研究进展综述[J]. 机械工程学报, 2024, 60(9): 168-188.
[3]	李继成, 陈广俊, 许金凯, 于化东. C/SiC复合材料激光超声复合微切削材料损伤机理与表面质量研究[J]. 机械工程学报, 2024, 60(9): 189-205.
[4]	李晗, 章程, 陈杰, 安庆龙, 陈明. SiC_f/SiC复合材料激光烧蚀辅助铣削材料去除机理与加工表面质量评价[J]. 机械工程学报, 2024, 60(9): 206-217.
[5]	刘鑫, 张俊, 徐斌斌, 刘弘光, 赵万华. 激光辅助铣削过程的预热温度场调控方法研究[J]. 机械工程学报, 2024, 60(9): 218-228.
[6]	郝明武, 姚鹏, 周嘉斌, 黎月明, 梁士通, 褚东凯, 黄传真. 皮秒激光切向修整青铜结合剂金刚石砂轮的影响因素研究[J]. 机械工程学报, 2024, 60(9): 229-240.
[7]	肖贵坚, 刘振扬, 贺毅, 刘岗, 邓忠才. 激光辅助CBN砂带磨削TC4钛合金材料去除行为及表面完整性研究[J]. 机械工程学报, 2024, 60(9): 241-253.
[8]	江安娜, 言兰, 王宁昌, 姜峰, 李卓, 温秋玲, 卢希钊, 黄辉. 能量场辅助激光诱导等离子体加工透明硬脆材料的研究现状及发展趋势[J]. 机械工程学报, 2024, 60(9): 254-272.
[9]	邱文哲, 张臻, 王鹏, 刘邓华, 魏世川, 张国军. 激光浸液诱导冲击调控电火花线切割热变形行为[J]. 机械工程学报, 2024, 60(9): 273-285.
[10]	张春波, 吴成军, 袁浩天. 等离子体作用下不同脉冲数超快激光烧蚀过程中化学反应机制的数值模拟[J]. 机械工程学报, 2024, 60(8): 94-106.
[11]	张赛凡, 李博, 轩福贞. 激光选区熔化过程声发射信号的降噪与分类预测方法[J]. 机械工程学报, 2024, 60(6): 163-176.
[12]	李春凯, 王嘉昕, 石玗, 代悦. GTAW熔池激光条纹动态行为与熔透预测方法研究[J]. 机械工程学报, 2024, 60(6): 236-244.
[13]	高凯, 罗攀, 谢进, 胡林, 陈彬, 杜荣华. 基于数据融合的混合动力汽车速度轮廓预测[J]. 机械工程学报, 2024, 60(6): 342-353.
[14]	宋军, 唐倩, 罗智超, 冯琪翔, 聂云飞, 任治好. 马氏体时效钢激光选区熔化成形过程介观尺度数值模拟[J]. 机械工程学报, 2024, 60(3): 282-295.
[15]	荣鹏, 成靖, 邓鸿文, 陶常安, 高川云, 冉先喆, 程序, 汤海波, 刘栋. 不同热处理对激光定向能量沉积制造TC4钛合金组织和拉伸性能的影响[J]. 机械工程学报, 2024, 60(20): 99-107.