硼酸酯与聚醚复配水溶液的摩擦学性能研究

doi:10.3901/JME.2016.03.110

机械工程学报 ›› 2016, Vol. 52 ›› Issue (3): 110-117.doi: 10.3901/JME.2016.03.110

硼酸酯与聚醚复配水溶液的摩擦学性能研究

谷国平, 张朝辉, 黄宝成, 李森, 王磊

北京交通大学机械与电子控制工程学院北京 100044

收稿日期:2015-02-14 修回日期:2015-11-04 出版日期:2016-02-05 发布日期:2016-02-05
通讯作者: 张朝辉，男，1972年出生，教授，博士研究生导师，主要研究方向为精密制造与摩擦学。 E-mail：zhhzhang@bjtu.edu.cn
作者简介:谷国平，男，1988年出生。主要研究方向为精密制造与摩擦学。 E-mail：12121325@bjtu.edu.cn

Tribological Properties of Aqueous Solutions with Polyether and Borate

GU Guoping, ZHANG Chaohui, HUANG Baocheng, LI Sen, WANG Lei

School of Mechanical Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044

Received:2015-02-14 Revised:2015-11-04 Online:2016-02-05 Published:2016-02-05

摘要/Abstract

摘要： 水的润滑性能较差，因此需要选取性能良好的水溶性添加剂对其摩擦性能进行改善。研究选取椰油酰胺聚氧乙烯醚(CPOE)和三乙醇胺硼酸酯(BN)作为添加剂，分别对CPOE和CPOE-BN水溶液的摩擦学性能进行研究。使用NGY-6纳米级膜厚测量仪测试两种溶液的成膜性能，结果表明两种溶液在低浓度下均具有良好的成膜能力。利用四球试验机对两种溶液的减摩抗磨性能、稳定性能和极压性能进行了研究，结果表明两种溶液在低浓度下均具有良好且稳定的减摩抗磨性能，BN的加入可以大大提高CPOE水溶液的减摩性能和高载荷下的抗磨性能。利用XPS技术对CPOE-BN磨痕表面的化学元素进行了分析，结果表明在磨痕的表面生成了氮化硼、硼化铁等化合物，起到了良好的减摩抗磨效果。研究表明，CPOE和BN具有良好的协同润滑效果，是一种具有良好工业应用前景的绿色水基润滑添加剂。

关键词: 成膜能力, 减摩抗磨, 三乙醇胺硼酸酯, 水基润滑, 椰油酰胺聚氧乙烯醚

Abstract: Due to poor lubrication performance of water, it is essential to select water-soluble additives with good functions to improve its tribological properties. Cocamide polyoxyethylene (CPOE) and triethanolamine borate (BN) are selected as additives to study the tribological properties of aqueous solutions with CPOE and CPOE-BN in the research. Film-forming abilities are measured by NGY-6 nanoscale film thickness gauge. Results show that both aqueous solutions have good film-forming abilities at a low concentration. Friction reducing and anti-wear properties, stabilities and extreme pressure are studied by MRS-10A four-ball tester. Results show that both solutions have a low and relatively stable friction coefficient. Friction coefficient is lower by the mixture of CPOE and BN than the single CPOE, so as the wear rate at a high load. At last, components of chemical elements on the surface of wear scar are analyzed by X-ray photoelectron spectroscopy. Results show that boron nitride, iron boride and other compounds are generated, playing an important role in reducing friction and wear. Studies indicate that CPOE and BN have a good synergistic effect on lubricating. They can be used in industry with a good prospect as green water-based lubricants.

Key words: cocamide polyoxyethylene (CPOE), film-forming ability, friction reducing and anti-wear, triethanolamine borate (BN), water-based lubricant

中图分类号:

TH117

谷国平, 张朝辉, 黄宝成, 李森, 王磊. 硼酸酯与聚醚复配水溶液的摩擦学性能研究[J]. 机械工程学报, 2016, 52(3): 110-117.

GU Guoping, ZHANG Chaohui, HUANG Baocheng, LI Sen, WANG Lei. Tribological Properties of Aqueous Solutions with Polyether and Borate[J]. Journal of Mechanical Engineering, 2016, 52(3): 110-117.

参考文献

[1] SULEK M， WASILEWSKI T，ZIEBA M. Tribological and physical-chemical properties of aqueous solutions of cationic surfactants[J]. Industrial Lubrication and Tribology，2010，62(5)：279-284.
[2] KINOSHITA H，NISHINA Y，ALIAS A A，et al. Tribological properties of monolayer graphene oxide sheets as water-based lubricant additives[J]. Carbon，2014，66：720-723.
[3] 许耀华，杨广彬，张晟卯，等. 水溶性纳米铜的制备及其摩擦学性能研究[J]. 摩擦学学报，2012，32(2)：165-170. XU Yaohua，YANG Guangbin，ZHANG Shengmao，et al. Preparation of water-soluble copper nanoparticles and evaluation of their tribological properties[J]. Tribology，2012，32(2)：165-170.
[4] SULEK M W，WASILEWSKI T. Influence of critical micelle concentration (CMC) on tribological properties of aqueous solutions of alkyl polyglucosides[J]. Tribology Transactions，2008，52(1)：12-20.
[5] TOMALA A，KARPINSKA A，WERNER W S M，et al. Tribological properties of additives for water-based lubricants[J]. Wear，2010，269(11)：804-810.
[6] 刘俊铭，张晨辉，张朝辉，等. 蓖麻油聚氧乙烯醚水基润滑液摩擦学特性研究[J]. 摩擦学学报，2011，31(3)：240-248. LIU Junming，ZHANG Chenhui，ZHANG Chaohui，et al. Lubricating properties of the aqueous solution of castor oil polyoxyethylene ether[J]. Tribology，2011，31(3)：240-248.
[7] 孙跃涛，张朝辉，刘思思. 月桂酸无规共聚醚水溶液减摩抗磨性能试验研究[J]. 机械工程学报，2012，47(23)：125-129. SUN Yuetao，ZHANG Chaohui，LIU Sisi. Study on friction-reducing and anti-wear performances of lauricacid random copolyether aqueous solutions[J]. Journal of Mechanical Engineering，2012，47(23)：125-129.
[8] ZHANG Chaohui，LIU Sisi，LIU Junming. Experimental study on friction reducing and anti-wear property of a water-based lubricant with polyether added[J]. Rare Metal Materials and Engineering，2012，41：276-279.
[9] ZHANG C H，LIU S S，SUN Y T. Tribological properties of aqueous solutions with lauric acid random copolyether (LPE) added[J]. Science China Technological Sciences，2013，56(12)：3007-3011.
[10] 王克华. 合成聚烷撑二醇金属加工液[J]. 合成润滑材料，2003，30(3)：39-43. WANG Kehua. Synthetic metalworking fluid of polyalkylene glycol[J].Synthetic Lubricants，2003，30(3)：39-43.
[11] 祁有丽，苏刚，陈馥婧，等. 水溶性聚醚酯摩擦学性能的研究[J]. 摩擦学学报，2011，31(3)：007. QI Youli，SU Gang，CHEN Fujing，et al. Tribological studies of a water –soluble polyether ester[J]. Tribology，2011，31(3)：007.
[12] 郑帼，肖长发. 聚醚系非离子表面活性剂结构与性能关系的研究[J]. 天津工业大学学报，2007，26(4)：19-24. ZHENG Guo，XIAO Changfa. Correlation between structure and properties of polyether nonionic surfactants[J].Journal of Tianjin Polytechnic University，2007，26(4)：19-24.
[13] 黄伟九，陈波水. 水溶性硼酸酯的摩擦学性能研究[J]. 机械工程学报，2001，37(5)：18-21.
HUANG Weijiu，CHEN Boshui. Study on the tribological properties of water-soluble borate[J]. Chinese Journal of Mechanical Engineering，2001，37(5)：18-21.
[14] 王松，岳文，王成彪，等. 渗氮 GCr15 钢在含氮硼酸酯添加剂润滑油作用下的摩擦学性能[J]. 机械工程学报，2012，48(19)：128-133. WANG Song，YUE Wen，WANG Chengbiao，et al. Tribological properties of plasma nitriding GCr15 steel under lubrication with borete containing nitrogen additive[J]. Journal of Mechanical Engineering，2012，48(19)：128-133.
[15] 方建华，陈波水，董凌，等. 含硼和氮的脂肪酸水基润滑添加剂的制备及其摩擦学性能[J]. 摩擦学学报，2003，3(23)：226-230. FANG Jianhua，CHEN Boshui，DONG Ling，et al. Synthesis and tribological behavior of boron-nitrogen modified ftty acid as water-based lubricating additive[J]. Tribology，2003，3(23)：226-230.
[16] 耿明，张朝辉，刘思思，等. 含氮硼酸酯在聚醚水溶液中的成膜性能[J]. 机械工程学报，2013，49(5)：84-89. GENG Ming，ZHANG Chaohui，LIU Sisi，et，al. Film-forming property of polyether aqueous solutions with nitrogenous boric acid ester[J]. Journal of Mechanical Engineering，2013，49(5)：84-89.
[17] 王亚杰，仲剑初，王洪志. 三乙醇胺硼酸酯的合成及其防锈性能[J]. 材料保护，2013，46(11)：29-31. WANG Yajie，ZHONG Jianchu，WANG Hongzhi. Synthesis and anti-rust properties of triethanolamine borate[J]. Journal of Materials Protection，2013，46(11)：29-31.
[18] WRIGHT M S，林亨耀. 四球磨损试验的磨损速率计算[J]. 润滑与密封，1991(2)：17-20. WRIGHT M S，LIN Hengyao. Wear rate calculation in the four ball wear test[J]. Lubrication Engineering. 1991(2)：17-20.
[19] GB/T 12583-1990. 润滑剂极压性能测定法(四球法). [S]. 北京：中国标准出版社，1998. GB/T 12583-1990. Method of measuring the extreme pressure properties of lubricant. (Four-ball method) [S]. Beijing：China Standard Press，1998.

硼酸酯与聚醚复配水溶液的摩擦学性能研究

Tribological Properties of Aqueous Solutions with Polyether and Borate

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