• CN:11-2187/TH
  • ISSN:0577-6686

›› 2013, Vol. 49 ›› Issue (8): 91-96.

• 论文 • 上一篇    下一篇

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民航客机7075-T6铝合金壁板的腐蚀特征与机制

苏景新; 邹阳; 陈康敏; 王志平; 关庆丰   

  1. 中国民航大学天津市民用航空器适航与维修重点实验室;江苏大学材料科学与工程学院
  • 发布日期:2013-04-20

Corrosion Mechanism and Characteristic of 7075-T6 Aluminum Alloy Panel on Airline Aircraft

SU Jingxin;ZOU Yang;CHEN Kangmin;WANG Zhiping;GUAN Qingfeng   

  1. Tianjin Key Laboratory for Civil Aircraft Airworthiness and Maintenance, Civil Aviation University of China College of Materials Science and Engineering, Jiangsu University
  • Published:2013-04-20

摘要: 为了研究民航客机结构的腐蚀机理,详细表征服役客机7075-T6铝合金壁板的腐蚀形貌、裂纹特征和腐蚀产物,并对其腐蚀机制进行探讨。利用扫描电子显微镜及附带能谱仪对壁板的完整涂层和已腐蚀(未剥落)涂层表面进行微观形貌和能谱分析。利用光学显微镜对壁板横截面金相样品进行详细观察,运用X射线物相衍射分析表面腐蚀残留物的物相。试验结果表明,客机7075铝合金壁板铆钉孔附近区域的表面涂层容易出现鼓泡、开裂等现象,并发生层状的剥落腐蚀,表面腐蚀形貌以微裂纹和龟裂为主,腐蚀产物以氢氧化物为主。铆钉孔附近区域表面下方可诱发大量不连续的阶梯状平行的沿晶应力腐蚀裂纹,裂纹引起的膨胀是表面涂层脱落的关键因素。此外,腐蚀介质中的Cl–、SO42–等有害离子对铝合金壁板的腐蚀具有明显的促进作用。

关键词: 7075铝合金, 剥蚀, 沿晶扩展, 应力腐蚀裂纹

Abstract: In order to provide an insight into the corrosion mechanisms of civil aircraft structural components, extensive investigation is performed to characterize the corrosion morphology, crack characteristics and corrosion productions of 7075-T6 aluminum alloy aircraft panel. Furthermore, the corrosion mechanisms are analyzed systematically. Microstructures and composition of coating surface on complete coating and coating corroded without peeling are analyzed respectively via scanning electron microscopy (SEM) and energy disperse spectrometer(EDS). Cross-section metallographic samples on aircraft panel are observed by optical microscope(OM), and X-ray diffraction(XRD) analysis of surface corrosion residue is also conducted. It has been found that for the surface coatings in the vicinity of rivet holes of 7075 aluminum alloy panel, bubble and cracking are easily to occur accompanied by stratiform exfoliation corrosion. Surface corrosion morphology is mainly made up of microcracks and chaps, and the major corrosion products are hydroxides. In the neighboring areas of rivet holes, a large number of discontinuous and stair-step paralleled stress corrosion cracks are induced under the surface coating. The inflation caused by crack expansion is a key factor determining surface coating desquamation. Moreover, Cl– and SO42– in corrosive solution can accelerate the atmospheric corrosion of aluminum alloy aircraft panel obviously.

Key words: 7075 aluminium alloy, Exfoliation corrosion, Intergranular expanding, Stress corrosion crack(SCC)

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