高强耐候钢在NaCl溶液中的腐蚀锈层特征和耐腐蚀性研究

doi:10.3901/JME.2017.20.045

机械工程学报 ›› 2017, Vol. 53 ›› Issue (20): 45-53.doi: 10.3901/JME.2017.20.045

扫码分享

高强耐候钢在NaCl溶液中的腐蚀锈层特征和耐腐蚀性研究

黄涛¹, 陈小平¹, 王向东¹, 汪兵¹, 王帆^1,2, 李向阳¹

1. 钢铁研究总院工程用钢研究所北京 100081;
2. 中国石油大学理学院北京 102249

收稿日期:2016-11-21 修回日期:2017-03-30 出版日期:2017-10-20 发布日期:2017-10-20
通讯作者: 陈小平(通信作者),男,1974年出生,博士,教授.主要研究方向金属材料表面处理与防护.E-mail:xiaoping118@sina.com
作者简介:黄涛,男,1988年出生,博士研究生.主要研究方向为钢铁材料的腐蚀与防护.E-mail:jxgahuangtao@126.com
基金资助:
国家重点基础研究发展计划资助项目（973计划，2014CB643300）。

A Study on the Rust Characteristics and Corrosion Resistance of High Strength Weathering Steels in NaCl Solution

HUANG Tao¹, CHEN Xiaoping¹, WANG Xiangdong¹, WANG Bing¹, WANG Fan^1,2, LI Xiangyang¹

1. Department of Structural Steel, Central Iron & Steel Research Institute, Beijing 100081;
2. School of Science, China University of Petroleum, Beijing 102249

Received:2016-11-21 Revised:2017-03-30 Online:2017-10-20 Published:2017-10-20

摘要/Abstract

摘要： 为了研究高强耐候钢Q450NQR1和B2在2.0%NaCl溶液中的腐蚀锈层特征，获得其耐腐蚀性规律。采用交流阻抗谱（Electrochemical impedance spectroscopy，EIS）、X射线衍射仪（X-ray diffracmeter，XRD）、扫描电镜（Scanning electron microscope，SEM）和电感耦合等离子体（Inductively coupled plasma，ICP）手段分析它们的腐蚀行为和锈层特征，并讨论合金元素Cu、Ni、Cr、Mo等对耐腐蚀性的影响。结果表明：B2耐候钢的耐蚀性要优于Q450NQR1耐候钢的，其锈层表现出较高的电荷转移电阻（R_t）特征；两种耐候钢的非连续性（Non-adherent rusts，NAR）和连续性（Adherent rusts，AR）型锈层物相组成分别一致，但含量有差别；NAR型锈层主要由大量的γ-FeOOH和少量的Fe₃O₄、α-FeOOH组成，紧贴基体的AR型锈层几乎全为Fe₃O₄。Cu、Ni、Cr、Mo合金元素在两种锈层中的分布不同，影响着NAR型锈和AR型锈的协同保护作用，从而改变了基体表面的锈层特征，稳定锈层的存在可显著抑制Cl^-渗入，有助于改善材料耐腐蚀性。

关键词: NaCl溶液, 合金元素, 交流阻抗谱, 耐候钢, 锈层

Abstract: In order to clarify the rust characteristics and the corrosion resistance rules, two kinds of weathering steels, Q450NQR1 and B2, have been investigated using 2.0% NaCl solution. The EIS, XRD, SEM and ICP are used for analysis. The effects of alloying elements, such as Cu, Ni, Cr, Mo on the corrosion resistance are also discussed. The results indicate that B2 shows greater corrosion resistance than that of Q450NQR1. And its rust layer behaves a higher charge transfer resistance (R_t). Besides, the two steels have similar constituents in both non-adherent rust (NAR) layers and in adherent rust (AR) layers, but different contents. The NAR layers for both steels consist of large portion of γ-FeOOH and few Fe₃O₄ and α-FeOOH; the AR layers, which are close to the base, consist almost entirely Fe₃O₄. The results of ICP show that Cu, Ni, Cr, Mo are distributed differently in NAR and AR layers and affect the cooperative protection between the two layers; thus, these phenomena stabilize the rust layers and change their characteristics on the base. These stable rust layers can significantly prohibit the penetration of Cl^-, which can improve the corrosion resistance.

Key words: alloying element, electrochemistry impedance spectrum, NaCl solution, rust layer, weathering steel

中图分类号:

TG172

黄涛, 陈小平, 王向东, 汪兵, 王帆, 李向阳. 高强耐候钢在NaCl溶液中的腐蚀锈层特征和耐腐蚀性研究[J]. 机械工程学报, 2017, 53(20): 45-53.

HUANG Tao, CHEN Xiaoping, WANG Xiangdong, WANG Bing, WANG Fan, LI Xiangyang. A Study on the Rust Characteristics and Corrosion Resistance of High Strength Weathering Steels in NaCl Solution[J]. Journal of Mechanical Engineering, 2017, 53(20): 45-53.

参考文献

[1] 高宏适. 日本桥梁用耐候钢的使用跟踪及维修技术[N].世界金属导报,2015-2-10:B12. GAO Hongshi. The use tracking and maintenance technology of Japan's bridges[N]. World Metal Bulletin, 2015-2-10:B12.
[2] 王祖滨,东涛. 低合金高强度钢[M]. 北京:原子能出版社,1996. WANG Zubin,DONG Tao. High strength low alloy steel[M]. Beijing:Atomic Energy Press,1996.
[3] 吴红艳,杜林秀,刘相华,等. 变形条件对Mn-Cu 耐候钢连续冷却相变的影响[J]. 机械工程学报,2007,43(9):145-150. WU Hongyan,DU Linxiu,LIU Xianghua,et al. Effect of deformation conditions on continuous cooling transformation of weathering steel with Mn-Cu[J]. Journal of Mechanical Engineering,2007,43(9):145-150.
[4] MONTOYA P,DIAZ I,GRANIZO N,et al. An study on accelerated corrosion testing of weathering steel[J]. Materials Chemistry and Physics,2013,142(1):220-228.
[5] MA Y T,LI Y,WANG F. Corrosion of low carbon steel in atmospheric environments of different chloride content[J]. Corrosion Science,2009,51(5):997-1006.
[6] 汪川,曹公旺,潘辰,等. 碳钢、耐候钢在3种典型大气环境中的腐蚀规律研究[J]. 中国腐蚀与防护学报,2016,36(1):39-46. WANG Chuan,CAO Gongwang, PAN Chen,et al. Atmospheric corrosion of carbon steel and weathering steel in three environments[J]. Journal of Chinese Society for Corrosion and Protection,2016,36(1):39-46.
[7] MORCILLO M,DIAZ I,CHICO B,et al. Weathering steels:From empirical development to scientific design[J]. Corrosion Science,2014,83:6-31.
[8] DIAZ I,CANO H,FUENTE D D L,et al. Atmospheric corrosion of Ni-advanced weathering steels in marine atmospheres of moderate salinity[J]. Corrosion Science,2013,76:348-360.
[9] ZHANG X,YANG S W,ZHANG W H,et al. Influence of outer rust layers on corrosion of carbon steel and weathering steel during wet-dry cycles[J]. Corrosion Science,2014,82:165-172.
[10] CANO H,NAFF D,MORCILLO M,et al. Characterization of corrosion products formed on Ni 2.4 wt%-Cu 0.5 wt%-Cr 0.5 wt% weathering steel exposed in marine atmospheres[J]. Corrosion Science,2014,87:438-451.
[11] CHEN X H,DONG J H,HAN E H,et al. Effect of Ni on the ion-selectivity of rust layer on low alloy steel[J]. Materials Letters,2007,61(19):4050-4053.
[12] 王树涛,杨善武,高克玮,等. 低合金耐候钢在含氯离子环境中的耐腐蚀性能[J]. 材料热处理学报,2008,29(4):170-175. WANG Shutao,YANG Shanwu,GAO Kewei,et al. Corrosion resistance of low alloying weathering steels in environment containing chloride ion[J]. Transactions of Materials and Heat Treatment,2008,29(4):170-175.
[13] 王国庆,魏丽芳,董春红,等. 不同品质怀地黄中金属元素含量的 ICP-MS测定及其比较[J]. 光谱学与光谱分析,2009,29(12):3392-3394. WANG Guoqing,WEI Lifang,DONG Chunhong,et al. Determination and comparison of metal elements in Huai radix rehmanniae at different grades by ICP-MS[J]. Spectroscopy and Spectral Analysis,2009,29(12):3392-3394.
[14] NISHIKATA A,YAMASHITA Y,KATAYAMA H,et al. An electrochemical impedance study on atmospheric corrosion of steels in a cyclic wet-dry condition[J]. Corrosion science,1995,37(12):2059-2069.
[15] 杨仲年,张昭,苏景新,等. 耐候钢在2.0%NaCl中性溶液中的腐蚀过程[J]. 金属学报,2005,41(8):860-864. YANG Zhongnian,ZHANG Zhao,SU Jingxin,et al. Corrosion processes of weathering steels in 2.0%NaCl neutral solutions[J]. Acta Metallurgica Sinica,2005,41(8):860-864.
[16] 汪兵,刘清友,毛新平,等. 稀土对碳素钢在0.3 mol/L NaCl溶液中耐蚀性能的影响[J]. 金属学报,2008,44(7):863-866. WANG Bing,LIU Qingyou,MAO Xinping,et al. Effect of rare earth on the corrosion resistance of carbon steel in 0.3mol/L NaCl solution[J]. Acta Metallurgica Sinica, 2008,44(7):863-866.
[17] 夏妍,曹发和,常林荣,等. 锈层下碳钢和耐候钢的微区和宏观腐蚀电化学行为[J]. 高等学校化学学报,2013,34(5):1246-1253. XIA Yan,CAO Fahe,CHANG Linrong,et al. Corrosion micro-and macro-electrochemical behavior of rusted carbon steel and weathering steel[J]. Chemical Journal of Chinese Universities,2013,34(5):1246-1253.
[18] 施锦杰,孙伟. 等效电路拟合钢筋锈蚀行为的电化学阻抗谱研究[J]. 腐蚀科学与防护技术,2011,23(5):388-392. SHI Jinjie,SUN Wei. Equivalent circuits fitting of electrochemical impedance spectroscopy for corrosion of reinforcing steel in concrete[J]. Corrosion Science and Protection Technology,2011,23(5):388-392.
[19] 吴俊升,林超,彭冬冬,等. Q345D低合金钢在海洋潮差区的腐蚀规律及电化学行为研究[J]. 机械工程学报,2016,52(20):30-37. WU Junsheng,LIN Chao,PENG Dongdong,et al. Electrochemical investigation and corrosion behavior of low alloy steel Q345D in marine tidal zone[J]. Journal of Mechanical Engineering,2016,52(20):30-37.
[20] WANG J,WANG Z Y,KE W. A study of the evolution of rust on weathering steel submitted to the Qinghai salt lake atmospheric corrosion[J]. Materials Chemistry and Physics,2013,139(1):225-232.
[21] GARCIA K E,MORALES A L,BARRERO C A,et al. New contributions to the understanding of rust layer formation in steels exposed to a total immersion test[J]. Corrosion Science,2006,48(9):2813-2830.
[22] STATMANN M,BOHNENKAMP K,RAMCHANDRAN T. The influence of copper upon the atmospheric corrosion of iron[J]. Corrosion Science,1987,27(9):905-926.
[23] YAMASHITA M,SHIMIZU T,KONISHI H,et al. Structure and protective performance of atmospheric corrosion product of Fe-Cr alloy film analyzed by Mössbauer spectroscopy and with synchrotron radiation X-rays[J]. Corrosion Science,2003,45(2):381-394.
[24] MELCHERS R E. A new interpretation of the corrosion loss processes for weathering steels in marine atmospheres[J]. Corrosion Science,2008,50(12):3446-3454.
[25] 木冠南,李向红,屈庆,等. 稀土铈(IV)离子和钼酸钠在盐酸溶液中对冷轧钢的缓蚀协同效应[J]. 化学学报,2004,62(24):2386-2390. MU Guannan,LI Xianghong,QU Qing,et al. Synergistic effect on corrosion inhibition by cerium(IV) ion and sodium molybdate for cold rolled steel in hydrochloric acid solution[J]. Acta Cheimica Sinica,2004,62(24):2386-2390.
[26] NASRAZADANI S,RAMAN A. Formation and transformation of magnetite (Fe₃O₄) on steel surfaces under continuous and cyclic water fog testing[J]. Corrosion,1993,49(4):294-298.
[27] NISHIMURA T,KATAYAMA H,NODA K, et al. Effect of Co and Ni on the corrosion behavior of low alloy steels in wet/dry environments[J]. Corrosion Science,2000,42(9):1611-1621.

高强耐候钢在NaCl溶液中的腐蚀锈层特征和耐腐蚀性研究

A Study on the Rust Characteristics and Corrosion Resistance of High Strength Weathering Steels in NaCl Solution

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 12

编辑推荐

Metrics

本文评价

[1]	王高见, 刘丽, 康丹丹, 叶延洪, 邓德安. Ni含量对高速列车转向架耐候钢焊缝金属微观组织、力学性能及腐蚀行为的影响[J]. 机械工程学报, 2024, 60(18): 163-172.
[2]	陈林, 戴宇恒, 崔健伟, 周庆飞, 岑耀东. 微合金化钢轨淬火工艺的优化及其疲劳裂纹扩展行为研究[J]. 机械工程学报, 2022, 58(14): 233-240.
[3]	孔祥霞, 翟军军, 孙凤莲. 电子封装用低银Sn-0.3Ag-0.7Cu钎料研究进展[J]. 机械工程学报, 2022, 58(12): 39-54.
[4]	罗来马, 黄科, 昝祥, 朱晓勇, 李萍, 吴玉程. 合金化改性钨基材料的组织和性能研究与发展[J]. 机械工程学报, 2018, 54(8): 117-128.
[5]	郑春雷, 张福成, 吕博, 但锐, 苏丽婷. 无碳化物贝氏体钢的滚动接触疲劳磨损行为[J]. 机械工程学报, 2018, 54(4): 176-185.
[6]	王晓虹, 谷晓燕, 孙大千. 钢/铝异种金属激光焊接头界面特性的研究^*[J]. 机械工程学报, 2017, 53(4): 26-33.
[7]	马宏驰, 刘智勇, 杜翠薇, 杨小佳, 李晓刚, 逄昆. SO₂质量分数对污染海洋大气环境中高强钢E690腐蚀行为的影响^*[J]. 机械工程学报, 2016, 52(16): 33-41.
[8]	吴红艳;杜林秀;刘相华;王国栋;董俊华;董杰. 变形条件对Mn-Cu耐候钢连续冷却相变的影响[J]. , 2007, 43(9): 145-150.
[9]	孙淑华;张振戎;熊毅;吕知清;厉勇;傅万堂;牧正志. 锰和硅添加对重度冷轧及退火后珠光体钢力学性能的影响[J]. , 2005, 41(5): 147-153.
[10]	刘贵立;张国英;曾梅光;钱存富. Co、Al对二次硬化钢微结构影响的穆谱研究[J]. , 2002, 38(12): 149-152.
[11]	孙大涌;薛侃时;徐佐仁;王滨;张静江;李晋. 锰低温钢中锰及合金元素的不平衡偏聚[J]. , 1998, 34(4): 1-6，14.
[12]	范大楠;王玉林;刘兆年;张宏祥;王书勤;李国俊. 合金阻挡层及对C/Cu复合材料性能影响的研究[J]. , 1990, 26(4): 59-63.