等离子喷涂树脂基体抗氧化材料及涂层的研究

doi:10.3901/JME.2025.10.100

机械工程学报 ›› 2025, Vol. 61 ›› Issue (10): 100-116.doi: 10.3901/JME.2025.10.100

• 特邀专栏：高端装备表面强化防护与再制造 • 上一篇

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等离子喷涂树脂基体抗氧化材料及涂层的研究

高藩^1,2,3, 何鑫^1,2, 柳彦博^1,2,3, 牟广义^1,2, 刘少璞^1,2, 刘玲^1,2,3, 马壮^1,2,3

1. 北京理工大学材料学院北京 100081;
2. 北京理工大学冲击环境材料技术国家级重点实验室北京 100081;
3. 北京理工大学重庆创新中心重庆 401120

收稿日期:2024-09-30 修回日期:2025-02-18 发布日期:2025-07-12
作者简介:高藩，男，2001年出生。主要研究方向为热喷涂及抗烧蚀涂层。E-mail：3220231645@bit.edu.cn;柳彦博(通信作者)，男，1978年出生，博士，副研究员，博士研究生导师。主要研究方向为热喷涂及特种功能陶瓷材料。E-mail：lyb197896@bit.edu.cn

Research on Plasma Spraying Resin Matrix Antioxidant Materials and Coatings

GAO Fan^1,2,3, HE Xin^1,2, LIU Yanbo^1,2,3, MOU Guangyi^1,2, LIU Shaopu^1,2, LIU Ling^1,2,3, MA Zhuang^1,2,3

1. School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081;
2. National Key Laboratory of Science and Technology on Material under Shock and Impact, Beijing Institute of Technology, Beijing 100081;
3. Chongqing Innovation Center, Beijing Institute of Technology, Chongqing 401120

Received:2024-09-30 Revised:2025-02-18 Published:2025-07-12

摘要/Abstract

摘要： 随着航空发动机的日益发展，燃烧室火焰温度的不断提高，广泛应用于航空发动机冷端部件的树脂基复合材料面临着更加严苛的氧化烧蚀环境，而在树脂基复合材料表面制备抗氧化烧蚀涂层则是一种有效可行的应对策略。在各类涂层方案及体系中，兼具隔热、抗氧化、应力缓冲等特点的多层结构体系受到广泛关注，该研究提出Al/NiCoCrAl/YSZ三层结构涂层，并使用酚醛树脂和SiO₂对YSZ进行改性，利用喷雾造粒的方法对改性后的复合粉体进行制备，使用大气等离子喷涂方法在碳纤维增强的聚酰亚胺基复合材料表面制备涂层样品。在热流密度为100 J/(m²·s)的氧乙炔燃流条件下，酚醛树脂含量为6wt.%改性的涂层的防护效果最佳，试样的线烧蚀率为4.42×10^-4 mm/s，质量烧蚀率为9×10^-6 g/s。

关键词: 树脂基复合材料, 抗氧化烧蚀, 多层复合涂层, 大气等离子喷涂, 氧乙炔烧蚀

Abstract: With the increasing development of aviation engines and the continuous increase of combustion chamber flame temperature, resin based composite materials widely used in cold end components of aviation engines face more severe oxidation and ablation environments. Preparing anti oxidation and ablation coatings on the surface of resin based composite materials is an effective and feasible response strategy. Among various coating schemes and systems, the multi-layer structure system with the characteristics of heat insulation, oxidation resistance, stress buffering, etc. has attracted wide attention. In this study, Al/NiCoCrAl/YSZ three-layer structure coating is proposed, and YSZ is modified by phenolic resin and SiO₂, the modified composite powder is prepared by spray granulation, and coating samples are prepared on the surface of carbon fiber reinforced polyimide matrix composites by atmospheric plasma spraying. Under ablation conditions of oxyacetylene combustion with a heat flux density of 100 J/(m²·s), the modified coating with a phenolic resin content of 6wt.% has the best protective effect. The line ablation rate and mass ablation rate of the sample are 4.42×10^-4 mm/s and 9×10^-6 g/s, respectively.

Key words: resin based composite materials, anti oxidation erosion, multilayer composite coating, atmospheric plasma spraying, oxygen acetylene ablation

中图分类号:

V258

高藩, 何鑫, 柳彦博, 牟广义, 刘少璞, 刘玲, 马壮. 等离子喷涂树脂基体抗氧化材料及涂层的研究[J]. 机械工程学报, 2025, 61(10): 100-116.

GAO Fan, HE Xin, LIU Yanbo, MOU Guangyi, LIU Shaopu, LIU Ling, MA Zhuang. Research on Plasma Spraying Resin Matrix Antioxidant Materials and Coatings[J]. Journal of Mechanical Engineering, 2025, 61(10): 100-116.

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等离子喷涂树脂基体抗氧化材料及涂层的研究

Research on Plasma Spraying Resin Matrix Antioxidant Materials and Coatings

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