铝/铜电弧熔钎焊接头界面组织及演变研究

doi:10.3901/JME.2020.06.017

机械工程学报 ›› 2020, Vol. 56 ›› Issue (6): 17-23.doi: 10.3901/JME.2020.06.017

• 铝与镁/铜合金的焊接 • 上一篇下一篇

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铝/铜电弧熔钎焊接头界面组织及演变研究

黄健康^1,2, 杨涛¹, 于晓全², 王梓懿², 樊丁^1,2

1. 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室兰州 730050;
2. 兰州理工大学材料科学与工程学院兰州 730050

收稿日期:2019-08-24 修回日期:2019-10-08 出版日期:2020-03-20 发布日期:2020-05-12
作者简介:黄健康,男,1981年出生,副教授。主要研究方向为异种金属焊接、焊接过程控制和焊接物理等,发表论文200余篇。E-mail:sr2810@163.com;
于晓全,男,1989年出生,博士研究生。主要研究方向为异种金属焊接及其界面行为,发表论文5篇。E-mail:yuxiaoquangood@163.com;
樊丁,男,1961年出生,教授,博士研究生导师。主要研究方向为焊接物理,焊接方法与智能控制及激光加工等,发表论文300余篇。E-mail:fand@lut.cn
基金资助:
国家自然科学基金资助项目（51865029）。

Study of Interfacial Microstructure and Phase Evolution of Al/Cu Arc Welding-brazing Joint

HUANG Jiankang^1,2, YANG Tao¹, YU Xiaoquan², WANG Ziyi², FAN Ding^1,2

1. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050;
2. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050

Received:2019-08-24 Revised:2019-10-08 Online:2020-03-20 Published:2020-05-12

摘要/Abstract

摘要： 采用旁路耦合电弧焊方法实现了铝合金与紫铜的熔钎焊，并研究焊后退火下铝/铜界面组织的演变。采用扫描电镜观察焊后及不同退火工艺下界面微观组织的形貌，同时，通过能谱仪及X射线衍射对界面的物相进行确定，并通过蒙特卡洛结合原胞自动机方法建立界面金属间化合物的热力学-动力学模型，分析了界面组织的演变行为。结果表明，通过旁路耦合电弧方法可实现铝/铜的熔钎焊，铝/铜焊接接头经250～400℃退火3 h后，界面处最终形成CuAl、Cu₉Al₄和CuAl₂三种金属间化合物，随着退火温度的增加，界面金属间化合物厚度呈线性增加，最大厚度为38.39 μm，铜-铝界面金属间化合物的形成由原子间互扩散和界面化学反应共同决定。

关键词: 铜/铝焊接接头, 退火, 微观组织, 界面演变

Abstract: Using a bypass coupled arc method, an aluminum plate is joined to a red copper plate, and the evolution of interfacial microstructure is studied after post-weld annealing. The morphologies of interfacial microstructure for welding and annealing state are observed by scanning electron microscopy, and the interfacial phase is identified by energy dispersive spectrometer and X-ray diffraction methods. The thermodynamic-dynamic model of intermetallic compounds at the interface is established by Monte Carlo combining Cellular Automata, and the evolution behavior of intermetallic compounds is analyzed. The results show that a welding-brazing joint can be obtain by bypass coupled arc method, three kinds of intermetallic compounds of CuAl, Cu₉Al₄, and CuAl₂ are formed at the interface of Al/Cu weld joint after annealing for 3 hours at 250-400 ℃. With the increase of annealing temperature, the intermetallic compound thickness at the interface increases, and the maximum thickness is 38.39μm. The inter-diffusion and interface chemical reaction determine the formation of intermetallic compounds at the copper-aluminum interface.

Key words: Cu/Al weld joint, annealing, microstructure, interface evolution

中图分类号:

TG146

黄健康, 杨涛, 于晓全, 王梓懿, 樊丁. 铝/铜电弧熔钎焊接头界面组织及演变研究[J]. 机械工程学报, 2020, 56(6): 17-23.

HUANG Jiankang, YANG Tao, YU Xiaoquan, WANG Ziyi, FAN Ding. Study of Interfacial Microstructure and Phase Evolution of Al/Cu Arc Welding-brazing Joint[J]. Journal of Mechanical Engineering, 2020, 56(6): 17-23.

参考文献

[1] MEHTA K P. A review on dissimilar friction stir welding of copper to aluminum:Process, properties and variants[J]. Materials and Manufacturing Processes,2015,31(3):233-254.
[2] 张建宇,姚金金,曾祥勇,等.铜包铝复合材料研究进展[J].中国有色金属学报,2014,24(5):1276-1282. ZHANG Jianyu,YAO Jinjin,ZENG Xiangyong,et al. Research progress of copper cladding aluminum composites[J]. The Chinese Journal of Nonferrous Metals,2014,24(5):1276-1282.
[3] 黄健康,王梓懿,梁菲菲,等.铝/铜异种金属熔钎焊焊接研究现状[J].电焊机,2019,49(1):20-23,57. HUANG Jiankang,WANG Ziyi,LIANG Feifei,et al. Research status of fusion brazing for Al/Cu dissimilar alloys[J]. Electric Welding Machine,2019,49(1):20-23,57.
[4] 董红刚,张旭超,杨继承,等.铝合金/黄铜异种金属电弧熔钎焊[J].中国机械工程,2014,25(8):1122-1125. DONG Honggang,ZHANG Xuchao,YANG Jicheng,et al. Arc-brazing of aluminum alloy to brass[J]. China Mechanical Engineering,2014,25(8):1122-1125.
[5] 姬峰,薛松柏,张满,等.时效对铜铝钎焊接头界面化合物和性能的影响[J].焊接学报,2012,33(5):21-24. JI Feng,XUE Songbai,ZHANG Man,et al. Effects of thermal aging on intermetallic compounds and properties of Cu/Al brazing joint[J]. Transactions of The China Welding Institution,2012,33(5):21-24.
[6] LI H,CHEN W,DONG L,et al. Interfacial bonding mechanism and annealing effect on Cu-Al joint produced by solid-liquid compound casting[J]. Journal of Materials Processing Technology,2017,252:795-803.
[7] GUEYDAN A,DOMENGÈS B,HUG E. Study of the intermetallic growth in copper-clad aluminum wires after thermal aging[J]. Intermetallics,2014,50:34-42.
[8] 李挺,黄健康,陈秀娟,等.旁路耦合微束等离子弧热特性及焊缝成形特点[J].焊接学报,2018,39(9):55-60. LI Ting,HUANG Jiankang,CHEN Xiujuan,et al. Thermal characteristics and weld formation of double electrode micro-plasma arc welding[J]. Transactions of the China Welding Institution,2018,39(9):55-60.
[9] 周相龙,石玗,朱明,等.铝/铜异种金属熔钎焊接头微观组织与力学性能[J].焊接学报,2018,39(5):59-62. ZHOU Xianglong,SHI Yu,ZHU Ming,et al. Microstructure and mechanical properties of Al/Cu dissimilar metals welding-brazing joint[J]. Transactions of the China Welding Institution,2018,39(5):59-62.
[10] LI Wenya,WEN Quan,YANG Xiawei,et al. Interface microstructure evolution and mechanical properties of Al/Cu bimetallic tubes fabricated by a novel friction-based welding technology[J]. Materials & Design,2017,134:383-393
[11] ZHOU L,LUO L Y,TAN C W,et al. Effect of welding speed on microstructural evolution and mechanical properties of laser welded-brazed Al/brass dissimilar joints[J]. Optics & Laser Technology,2017,98:234-246.
[12] TONG M,LI D,LI Y. A q-state potts model-based monte carlo method used to model the isothermal austenite-ferrite transformation under non-equilibrium interface condition[J]. Acta Materialia,2005,53(5):1485-1497.
[13] LIANG S M,SCHMID-FETZER R. Thermodynamic assessment of the Al-Cu-Zn system,part II:Al-Cu binary system[J]. Calphad,2015,51:252-260.
[14] READ W T,SHOCKLEY W. Dislocation models of crystal grain boundaries[J]. Physical Review,1950,78(3):275-289.
[15] WINEGARD W C. Fundamentals of the solidification of metals[J]. Metallurgical Reviews,1961,6(1):57-100.
[16] XIAO N,TONG M,LAN Y,et al. Coupled simulation of the influence of austenite deformation on the subsequent isothermal austenite-ferrite transformation[J]. Acta Materialia,2006,54(5):1265-1278.

铝/铜电弧熔钎焊接头界面组织及演变研究

Study of Interfacial Microstructure and Phase Evolution of Al/Cu Arc Welding-brazing Joint

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